3,5-二叔丁基邻苯醌合成路线 （共 229 条）
反应条件
in N,N-dimethyl-formamide Ar-atmosphere; dropwise addn. of 1 equiv. quinone to Ge-compd. (pptn.);
参考文献
Mazieres; Lavayssiere; Dousse; Satge
Inorganica Chimica Acta, 1996 , vol. 252, # 1-2 p. 25 - 32
反应条件
in dichloromethane N2-atmosphere; 1-4 equiv. quinone; sepn. of pptd. Ph4Sn, evapn.;
参考文献
Brown, Martyn A.; McGarvey, Bruce R.; Ozarowski, Andrzej; Tuck, Dennis G.
Journal of Organometallic Chemistry, 1998 , vol. 550, # 1-2 p. 165 - 172
反应条件
in pentane mixing of solns. (20°C), treatment (40 min); further product; crystn., sepn.;
参考文献
Razuvaev, G. A.; Abakumov, G. A.; Gladyshev, E. N.; Bayushkin, P. Ya.; Tsaryapkin, V. A.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, p. 1888 - 1893
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 9 p. 2138 - 2144
反应条件
3,3-dimethyldioxirane in acetone Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Crandall, Jack K.; Zucco, Martine; Scott Kirsch; Coppert, David M.
Tetrahedron Letters, 1991 , vol. 32, # 40 p. 5441 - 5444
反应条件
nitric acid in acetic acid
参考文献
Vertex Pharmaceuticals Incorported
Patent: US2011/98311 A1, 2011 ;
Title/Abstract Full Text Show Details
Vertex Pharmaceuticals Incorporated
Patent: US2012/309758 A1, 2012 ;
US 20120309758 A1
反应条件
in benzene inert atmosphere; heating (ampoule fused, 80°C, 48 h); further products;
参考文献
Journal of Organometallic Chemistry, , vol. 443, # 1 p. 43 - 49
参考文献
EP2730554 A1, ;
Page/Page column ;
反应条件
sodium in tetrahydrofuran addn. of Na to a soln. of quinone in THF at 20°C (20 h, blue-coloration), then addn. of Ge-compd., standing at 20°C for 2 h; concn. under reduced pressure, treatment of residue with MeOH, filtn., filtrate contains germane and germylcatechole (GLC);
参考文献
Riviere, P.; Castel, A.; Ko, Y. H.; Desor, D.
Journal of Organometallic Chemistry, 1990 , vol. 386, # 2 p. 147 - 156
反应条件
in benzene-d6 (high vacuum system), 12h at 150°C; detected by NMR, GC/MS;
参考文献
Journal of Organometallic Chemistry, , vol. 315, p. 157 - 164
反应条件
sodium in tetrahydrofuran addn. of Na to a soln. of quinone in THF at 20°C (20 h, blue-coloration), then addn. of Ge-compd., standing at 20°C for 2 h; concn. under reduced pressure, treatment of residue with MeOH, filtn., filtrate contains germane and germylcatechole (GLC);
参考文献
Riviere, P.; Castel, A.; Ko, Y. H.; Desor, D.
Journal of Organometallic Chemistry, 1990 , vol. 386, # 2 p. 147 - 156
