3,5-二叔丁基邻苯醌合成路线 （共 229 条）
反应条件
in tetrahydrofuran addn. of Ge-compd. to a soln. of quinone in THF, stirring at 20°C for 1.30 h; concn. under reduced pressure, then addn. of MeOH gives digermane, concn. of filtrate, monitored by GLC;
参考文献
Riviere, P.; Castel, A.; Ko, Y. H.; Desor, D.
Journal of Organometallic Chemistry, 1990 , vol. 386, # 2 p. 147 - 156
反应条件
in benzene-d6 inert atmosphere; heating (ampoule fused, 100°C, 48 h); further products;
参考文献
Journal of Organometallic Chemistry, , vol. 443, # 1 p. 43 - 49
反应条件
boron trifluoride diethyl etherate
参考文献
Chemistry of Heterocyclic Compounds (New York, NY, United States), , vol. 19, # 4 p. 364 - 368
Khimiya Geterotsiklicheskikh Soedinenii, , # 4 p. 454 - 458
反应条件
in benzene (high vacuum system), soln. of the quinone added to a soln. of the germylene, 20°C until color disappeared; solvent removed under vacuum;
参考文献
Journal of Organometallic Chemistry, , vol. 315, p. 157 - 164
反应条件
in benzene byproducts: HCl; Ge-compd. soln. addn. (dropwise) to org. compd. soln. (HCl sepn. at 20°C), stirring (48 h, 20°C). mixt. concn. (reduced pressure), pentane addn., keeping; pptn. on keeping 2 h at -30°C, ppt. filtration off, filtrate concn. (reduced pressure), CDCl3 addn., paper chromy.;
参考文献
Phosphorus, Sulfur and Silicon and the Related Elements, , vol. 82, # 1-4 p. 181 - 194
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene in benzene-d6 byproducts: DBU*HCl; inert atmosphere (Ar or N2); 20°C, 17 h; (1)H-NMR; evapn., pentane addn., filtn.;
参考文献
Journal of Organometallic Chemistry, , vol. 358, p. 77 - 94
反应条件
in benzene-d6 inert atmosphere (Ar or N2); 100°C, 12 h; not isolated; (1)H-NMR;
参考文献
Journal of Organometallic Chemistry, , vol. 358, p. 77 - 94
反应条件
in benzene byproducts: Me2NNMe2, Me2NH, PhNMe2; inert atmosphere (Ar or N2); 20°C, 3 h; fractional distn.;
参考文献
Journal of Organometallic Chemistry, , vol. 358, p. 77 - 94
反应条件
in benzene Kinetics; byproducts: Me2NNMe2, Me2NH, PhNMe2; inert atmosphere (Ar or N2); 20°C; not isolated; 1(H)-NMR, IR, MS identification;
参考文献
Riviere-Baudet, M.; Riviere, P.; Khallaayoun, A.; Satge, J.; Rauzy, K.
Journal of Organometallic Chemistry, 1988 , vol. 358, p. 77 - 94
反应条件
in benzene byproducts: HCl; heating in a sealed tube at 80 ° C for 12 h,; concn. (reduced pressure), anal. (IR, H-NMR, MS); 13percent starting germane;
参考文献
Journal of Organometallic Chemistry, , vol. 339, p. 51 - 60
