2-氨基-9H-噻吨-9-酮合成路线 （共 18 条）
反应条件
iron; ammonium chloride in ethanol; water 3 h; Heating;
参考文献
Moon, Jung-Kyen; Park, Jung-Won; Lee, Woo Song; Kang, Young-Jin; Chung, Hyun-A.; Shin, Mi-Seon; Yoon, Yong-Jin; Park, Ki Hun
Journal of Heterocyclic Chemistry, 1999 , vol. 36, # 3 p. 793 - 798
反应条件
dicyclohexyl(2',4',6'-triisopropyl-5-methoxy-3,4,6-trimethyl-[1,1'-biphenyl]-2-yl)phosphine; C50H70NO4PPdS; C50H70NO4PPdS; dicyclohexyl(2',4',6'-triisopropyl-4-methoxy-3,5,6-trimethyl-[1,1'-biphenyl]-2-yl)phosphine; ammonia; sodium t-butanolate in 1,4-dioxane T=80°C; 24 h; Inert atmosphere;
参考文献
Cheung, Chi Wai; Surry, David S.; Buchwald, Stephen L.
Organic Letters, 2013 , vol. 15, # 14 p. 3734 - 3737
反应条件
1: 80 percent / polyphosphoric acid, acetic acid, phosphorus pentoxide, phosphoric acid / 1 h / 140 °C 2: 90 percent / Fe, NH4Cl / ethanol; H2O / 3 h / Heating View Scheme
参考文献
Mayer,F.
Chemische Berichte, 1909 , vol. 42, p. 3055
反应条件
1: 83 percent / EtONa / ethanol; dimethylformamide / 3 h / Heating 2: 80 percent / polyphosphoric acid, acetic acid, phosphorus pentoxide, phosphoric acid / 1 h / 140 °C 3: 90 percent / Fe, NH4Cl / ethanol; H2O / 3 h / Heating View Scheme
参考文献
Moon, Jung-Kyen; Park, Jung-Won; Lee, Woo Song; Kang, Young-Jin; Chung, Hyun-A.; Shin, Mi-Seon; Yoon, Yong-Jin; Park, Ki Hun
Journal of Heterocyclic Chemistry, 1999 , vol. 36, # 3 p. 793 - 798
反应条件
1: 83 percent / EtONa / ethanol; dimethylformamide / 3 h / Heating 2: 80 percent / polyphosphoric acid, acetic acid, phosphorus pentoxide, phosphoric acid / 1 h / 140 °C 3: 90 percent / Fe, NH4Cl / ethanol; H2O / 3 h / Heating View Scheme
参考文献
Mayer,F.
Chemische Berichte, 1909 , vol. 42, p. 3055
反应条件
1: 1) anhyd. K2CO3 / 1) water, methanol, reflux, 2) methanol, 10 h, reflux 2: 70 percent / conc. H2SO4 / 100 - 105 °C 3: 80 percent / stannous chloride, conc. HCl / acetic acid / 5 h / Heating View Scheme
参考文献
Arur, P. V.; Kulkarni, Sheshgiri N.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1981 , vol. 20, # 1 p. 50 - 52
反应条件
1: 70 percent / conc. H2SO4 / 100 - 105 °C 2: 80 percent / stannous chloride, conc. HCl / acetic acid / 5 h / Heating View Scheme
参考文献
Arur, P. V.; Kulkarni, Sheshgiri N.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1981 , vol. 20, # 1 p. 50 - 52
反应条件
1: 1) anhyd. K2CO3 / 1) water, methanol, reflux, 2) methanol, 10 h, reflux 2: 70 percent / conc. H2SO4 / 100 - 105 °C 3: 80 percent / stannous chloride, conc. HCl / acetic acid / 5 h / Heating View Scheme
参考文献
Arur, P. V.; Kulkarni, Sheshgiri N.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1981 , vol. 20, # 1 p. 50 - 52
参考文献
Mayer,F.
Chemische Berichte, 1909 , vol. 42, p. 3055
参考文献
McClelland; Peters
Journal of the Chemical Society, 1947 , p. 1229,1233
