反式-1,4-环已二甲酸甲酯合成路线 (共 18 条)
反应条件
1: in diethyl ether T=0°C; 2: With hydrogen; palladium on activated charcoal in ethyl acetate T=20°C; Further stages.;
参考文献
Takimoto; Mori
Journal of the American Chemical Society, 2001 , vol. 123, # 12 p. 2895 - 2896
反应条件
ultraviolettes Licht;
参考文献
Chemische Berichte, , vol. 47, p. 1805
反应条件
1: methanol With thionyl chloride T=-30 - 20°C; 1.5 h; 2: trans-cyclohexane-1,4-dicarboxylic acid T=20°C; 17 h;
参考文献
EP1582521 A1, ;
Page/Page column 116 ;
反应条件
1.1: Ni(cod)2; DBU / tetrahydrofuran / 7 h / 0 °C / 760.05 Torr 1.2: 50 percent / Me2Zn / tetrahydrofuran / 2 h / 0 °C 2.1: diethyl ether / 0 °C 2.2: 100 percent / H2 / Pd/C / ethyl acetate / 20 °C View Scheme
参考文献
Journal of the American Chemical Society, , vol. 123, # 12 p. 2895 - 2896
参考文献
Journal of the American Chemical Society, , vol. 70, p. 3177
反应条件
T=13°C; Isomerization; 2 h;
参考文献
Mikhaleva; Kuznetsova
Chemistry of Heterocyclic Compounds, 1999 , vol. 35, # 3 p. 310 - 315
反应条件
1: hydrogen chloride; acetic acid / Hydrogenation.weiteres Reagens: Platin; Behandlung des Reaktionsprodukts mit warmer wss. Natronlauge oder warmer wss. Salzsaeure 2: sulfuric acid; methanol View Scheme
参考文献
Helvetica Chimica Acta, , vol. 21, p. 141
反应条件
methanol; sulfuric acid
参考文献
Helvetica Chimica Acta, , vol. 21, p. 141
反应条件
T=25°C; sowie bei 35grad, 45grad und 55grad; Rate constant;
参考文献
Journal of the American Chemical Society, , vol. 72, p. 4406,4408
参考文献
Justus Liebigs Annalen der Chemie, , vol. 245, p. 170,172