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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
甲基苯基丙二酸二乙酯
合成路线
（共 38 条）
1449510-58-0
+
609-08-5
甲基丙二酸二乙酯
→
反应条件
34009-61-5
甲基苯基丙二酸二乙酯
反应条件
1: methyl malonic acid diethylester With sodium hydride in N,N-dimethyl-formamide; mineral oil T=0 - 20°C; 0.166667 h; 2: 2,6-dimethoxyphenyl(phenyl)iodonium triflate in N,N-dimethyl-formamide; mineral oil T=0 - 20°C; chemoselective reaction;
参考文献
Malmgren, Joel; Santoro, Stefano; Jalalian, Nazli; Himo, Fahmi; Olofsson, Berit
Chemistry - A European Journal, 2013 , vol. 19, # 31 p. 10334 - 10342
1449510-53-5
+
609-08-5
甲基丙二酸二乙酯
→
反应条件
34009-61-5
甲基苯基丙二酸二乙酯
反应条件
1: methyl malonic acid diethylester With sodium hydride in N,N-dimethyl-formamide; mineral oil T=0 - 20°C; 0.166667 h; 2: 2,6-dimethylphenyl(phenyl)iodonium triflate in N,N-dimethyl-formamide; mineral oil T=0 - 20°C; chemoselective reaction;
参考文献
Malmgren, Joel; Santoro, Stefano; Jalalian, Nazli; Himo, Fahmi; Olofsson, Berit
Chemistry - A European Journal, 2013 , vol. 19, # 31 p. 10334 - 10342
71-43-2
苯
→
反应条件
34009-61-5
甲基苯基丙二酸二乙酯
反应条件
1.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 0.33 h / -78 - 20 °C 2.1: sodium hydride / N,N-dimethyl-formamide; mineral oil / 0.17 h / 0 - 20 °C 2.2: 0 - 20 °C View Scheme
参考文献
Malmgren, Joel; Santoro, Stefano; Jalalian, Nazli; Himo, Fahmi; Olofsson, Berit
Chemistry - A European Journal, 2013 , vol. 19, # 31 p. 10334 - 10342
120976-84-3
+
609-08-5
甲基丙二酸二乙酯
→
反应条件
83026-49-7
+
34009-61-5
甲基苯基丙二酸二乙酯
反应条件
1: methyl malonic acid diethylester With sodium hydride in N,N-dimethyl-formamide; mineral oil T=0 - 20°C; 0.166667 h; 2: phenyl(p-tolyl)iodonium trifluoromethanesulfonate in N,N-dimethyl-formamide; mineral oil T=0 - 20°C; Overall yield = 64 percent; chemoselective reaction;
参考文献
Malmgren, Joel; Santoro, Stefano; Jalalian, Nazli; Himo, Fahmi; Olofsson, Berit
Chemistry - A European Journal, 2013 , vol. 19, # 31 p. 10334 - 10342
609-08-5
甲基丙二酸二乙酯
→
反应条件
118657-12-8
+
34009-61-5
甲基苯基丙二酸二乙酯
反应条件
1: methyl malonic acid diethylester With sodium hydride in N,N-dimethyl-formamide; mineral oil T=0 - 20°C; 0.166667 h; 2: 2-methoxyphenyl(phenyl)iodonium triflate in N,N-dimethyl-formamide; mineral oil T=0 - 20°C; Overall yield = 61 percent; chemoselective reaction;
参考文献
Malmgren, Joel; Santoro, Stefano; Jalalian, Nazli; Himo, Fahmi; Olofsson, Berit
Chemistry - A European Journal, 2013 , vol. 19, # 31 p. 10334 - 10342
1449510-52-4
+
609-08-5
甲基丙二酸二乙酯
→
反应条件
1449510-61-5
+
34009-61-5
甲基苯基丙二酸二乙酯
反应条件
1: methyl malonic acid diethylester With sodium hydride in N,N-dimethyl-formamide; mineral oil T=0 - 20°C; 0.166667 h; 2: 2,4-dimethylphenyl(phenyl)iodonium triflate in N,N-dimethyl-formamide; mineral oil T=0 - 20°C; Overall yield = 52 percent; chemoselective reaction;
参考文献
Malmgren, Joel; Santoro, Stefano; Jalalian, Nazli; Himo, Fahmi; Olofsson, Berit
Chemistry - A European Journal, 2013 , vol. 19, # 31 p. 10334 - 10342
144930-49-4
+
609-08-5
甲基丙二酸二乙酯
→
反应条件
83026-45-3
+
34009-61-5
甲基苯基丙二酸二乙酯
反应条件
1: methyl malonic acid diethylester With sodium hydride in N,N-dimethyl-formamide; mineral oil T=0 - 20°C; 0.166667 h; 2: (2,5-dimethylphenyl)(phenyl)iodonium triflate in N,N-dimethyl-formamide; mineral oil T=0 - 20°C; Overall yield = 95 percent; chemoselective reaction;
参考文献
Malmgren, Joel; Santoro, Stefano; Jalalian, Nazli; Himo, Fahmi; Olofsson, Berit
Chemistry - A European Journal, 2013 , vol. 19, # 31 p. 10334 - 10342
609-08-5
甲基丙二酸二乙酯
→
反应条件
34009-61-5
甲基苯基丙二酸二乙酯
反应条件
potassium tert-butylate; iodine 1) DMSO, r.t., 2 h, 2) Et2O, EtOAc, r.t., 2.5 h; Yield given. Multistep reaction;
参考文献
Deutsch; Bartoszek; Schneider; Zabel; Niclas
Advanced Synthesis and Catalysis, 1997 , vol. 339, # 3 p. 261 - 265
214214-66-1
→
反应条件
34009-61-5
甲基苯基丙二酸二乙酯
反应条件
Co(III){(DO)(DOH)pn}Br2; nBu4NPF6 in N,N-dimethyl-formamide Electrolysis;
参考文献
Tahara, Keishiro; Chen, Yi; Pan, Ling; Masuko, Takahiro; Shimakoshi, Hisashi; Hisaeda, Yoshio
Chemistry Letters, 2011 , vol. 40, # 2 p. 177 - 179
83-13-6
苯基丙二酸二乙酯
→
反应条件
34009-61-5
甲基苯基丙二酸二乙酯
反应条件
1.1: sodium hydride / tetrahydrofuran / 20 °C 1.2: 4 h / 85 °C 2.1: Co(III){(DO)(DOH)pn}Br2; nBu4NPF6 / N,N-dimethyl-formamide / Electrolysis View Scheme
参考文献
Tahara, Keishiro; Chen, Yi; Pan, Ling; Masuko, Takahiro; Shimakoshi, Hisashi; Hisaeda, Yoshio
Chemistry Letters, 2011 , vol. 40, # 2 p. 177 - 179
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