顺-11-十四碳烯-1-醇合成路线 （共 34 条）
反应条件
1: 90 percent / acetonitrile
2: DMSO, NaH / tetrahydrofuran / 0.5 h
View Scheme
参考文献
Horiike; Tanouchi; Hirano
Agricultural and Biological Chemistry, 1980 , vol. 44, # 2 p. 257 - 261
反应条件
1: 1.) B2H6, 2.) H2O2/3N NaOH / 1.) diglyme, 5h, 2.) room temperature, overnight
2: 85 percent / PBr3 / benzene / 5 h / Ambient temperature
3: 22 g / acetonitrile / 8 h / Heating
4: 1.) potassium tert-butanolate / 1.) DMF, 20 deg C, 3h, 2.) 5h
5: LiAlH4 / diethyl ether / 3 h / Heating
View Scheme
参考文献
Dzhemilev, U. M.; Balezina, G. G.; Volkova, L. A.; Krivonogov, V. P.; Tolstikov, G. A.
Chemistry of Natural Compounds, 1980 , vol. 16, # 1 p. 82 - 85
Khimiya Prirodnykh Soedinenii, 1980 , vol. 16, # 1 p. 97 - 102
反应条件
1: 22 g / acetonitrile / 8 h / Heating
2: 1.) potassium tert-butanolate / 1.) DMF, 20 deg C, 3h, 2.) 5h
3: LiAlH4 / diethyl ether / 3 h / Heating
View Scheme
参考文献
Dzhemilev, U. M.; Balezina, G. G.; Volkova, L. A.; Krivonogov, V. P.; Tolstikov, G. A.
Chemistry of Natural Compounds, 1980 , vol. 16, # 1 p. 82 - 85
Khimiya Prirodnykh Soedinenii, 1980 , vol. 16, # 1 p. 97 - 102
反应条件
1: 1.) B2H6, 2.) H2O2/3N NaOH / 1.) diglyme, 5h, 2.) room temperature, overnight
2: H2/RaNi / ethyl acetate / 4 h / 80 °C / 76000.1 Torr
3: 85 percent / PBr3 / benzene / 5 h / Ambient temperature
4: 22 g / acetonitrile / 8 h / Heating
5: 1.) potassium tert-butanolate / 1.) DMF, 20 deg C, 3h, 2.) 5h
6: LiAlH4 / diethyl ether / 3 h / Heating
View Scheme
参考文献
Dzhemilev, U. M.; Balezina, G. G.; Volkova, L. A.; Krivonogov, V. P.; Tolstikov, G. A.
Chemistry of Natural Compounds, 1980 , vol. 16, # 1 p. 82 - 85
Khimiya Prirodnykh Soedinenii, 1980 , vol. 16, # 1 p. 97 - 102
反应条件
1: 1.) potassium tert-butanolate / 1.) DMF, 20 deg C, 3h, 2.) 5h
2: LiAlH4 / diethyl ether / 3 h / Heating
View Scheme
参考文献
Dzhemilev, U. M.; Balezina, G. G.; Volkova, L. A.; Krivonogov, V. P.; Tolstikov, G. A.
Chemistry of Natural Compounds, 1980 , vol. 16, # 1 p. 82 - 85
Khimiya Prirodnykh Soedinenii, 1980 , vol. 16, # 1 p. 97 - 102
反应条件
1: H2/RaNi / ethyl acetate / 4 h / 80 °C / 76000.1 Torr
2: 85 percent / PBr3 / benzene / 5 h / Ambient temperature
3: 22 g / acetonitrile / 8 h / Heating
4: 1.) potassium tert-butanolate / 1.) DMF, 20 deg C, 3h, 2.) 5h
5: LiAlH4 / diethyl ether / 3 h / Heating
View Scheme
参考文献
Dzhemilev, U. M.; Balezina, G. G.; Volkova, L. A.; Krivonogov, V. P.; Tolstikov, G. A.
Chemistry of Natural Compounds, 1980 , vol. 16, # 1 p. 82 - 85
Khimiya Prirodnykh Soedinenii, 1980 , vol. 16, # 1 p. 97 - 102
反应条件
1: 90 percent / H2SO4 / 24 h / Heating
2: 70 percent / PCC, NaOAc / CH2Cl2 / 24 h / Ambient temperature
3: n-BuLi / toluene / 2 h / 25 °C
4: lithium aluminium hydride / tetrahydrofuran / 4 h / Heating
View Scheme
参考文献
Vinczer, Peter; Juvancz, Zoltan; Novak, Lajos; Szantay, Csaba
Acta Chimica Hungarica, 1988 , vol. 125, # 6 p. 797 - 820
反应条件
1: 92 percent / 2N NaOH / 5 h / Heating
2: 90 percent / H2SO4 / 24 h / Heating
3: 70 percent / PCC, NaOAc / CH2Cl2 / 24 h / Ambient temperature
4: n-BuLi / toluene / 2 h / 25 °C
5: lithium aluminium hydride / tetrahydrofuran / 4 h / Heating
View Scheme
参考文献
Vinczer, Peter; Juvancz, Zoltan; Novak, Lajos; Szantay, Csaba
Acta Chimica Hungarica, 1988 , vol. 125, # 6 p. 797 - 820
反应条件
1: n-BuLi / toluene / 2 h / 25 °C
2: lithium aluminium hydride / tetrahydrofuran / 4 h / Heating
View Scheme
参考文献
Vinczer, Peter; Juvancz, Zoltan; Novak, Lajos; Szantay, Csaba
Acta Chimica Hungarica, 1988 , vol. 125, # 6 p. 797 - 820
反应条件
1: (i) Na<N(SiMe3)2>, THF, (ii) /BRN= 1746480/
2: 9-BBN / tetrahydrofuran
View Scheme
参考文献
Bestmann; Kantardjiew; Roesel; et al.
Chemische Berichte, 1978 , vol. 111, # 1 p. 248 - 253
