(Z)-11-十六碳烯-1-乙酸盐合成路线 （共 74 条）
反应条件
1: PBr3 / benzene 2: (i) O3, (ii) NaBH4, MeOH 3: pyridine 4: (i) Mg, (ii) /BRN= 1760288/ View Scheme
参考文献
Tetrahedron Letters, , vol. No.50, p. 4851 - 4854
反应条件
1: KBH4, AcOH / benzene 2: (i) TsNHNH2, (ii) NaBH3CN 3: PBr3 / benzene 4: (i) Mg, (ii) /BRN= 1760288/ View Scheme
参考文献
Tetrahedron Letters, , vol. No.50, p. 4851 - 4854
反应条件
1: (i) O3, cyclohexane, MeOH, (ii) H2, Lindlar catalyst 2: KBH4, AcOH / benzene 3: (i) TsNHNH2, (ii) NaBH3CN 4: PBr3 / benzene 5: (i) Mg, (ii) /BRN= 1760288/ View Scheme
参考文献
Tetrahedron Letters, , vol. No.50, p. 4851 - 4854
反应条件
1: (i) TsNHNH2, (ii) NaBH3CN 2: PBr3 / benzene 3: (i) Mg, (ii) /BRN= 1760288/ View Scheme
参考文献
Tetrahedron Letters, , vol. No.50, p. 4851 - 4854
反应条件
1: (i) iBu2AlH, heptane, Et2O, (ii) (oxidation) 2: PBr3 / benzene 3: (i) O3, (ii) NaBH4, MeOH 4: pyridine 5: (i) Mg, (ii) /BRN= 1760288/ View Scheme
参考文献
Tetrahedron Letters, , vol. No.50, p. 4851 - 4854
反应条件
1: 96 percent / LiAlH4 / diethyl ether / 5 h 2: 98.5 percent / pyridine / benzene / 4 h / Heating View Scheme
参考文献
Journal of the Indian Chemical Society, , vol. 67, # 7 p. 565 - 567
Chemische Berichte, , vol. 113, # 12 p. 3898 - 3903
反应条件
1: 90 percent / acetonitrile 2: 63 percent / DMSO, NaH / tetrahydrofuran / 0.5 h 3: pyridine View Scheme
参考文献
Agricultural and Biological Chemistry, , vol. 44, # 2 p. 257 - 261
反应条件
1: 63 percent / DMSO, NaH / tetrahydrofuran / 0.5 h 2: pyridine View Scheme
参考文献
Agricultural and Biological Chemistry, , vol. 44, # 2 p. 257 - 261
反应条件
1: 54 percent / KOH / H2O; methanol / 24 h / Ambient temperature 2: 95 percent / 6.5 h / -5 - 0 °C View Scheme
参考文献
Chemistry of Natural Compounds, , vol. 18, # 2 p. 219 - 224
Khimiya Prirodnykh Soedinenii, , vol. 18, # 2 p. 239 - 245
反应条件
1: diethyl ether / 4 h / 0 - 2 °C 2: 79 percent / pyridine / 1.) -5 deg C, 6 h; 2.) 0 deg C, 12 h 3: 53 percent / sodium iodide, zinc dust / tetrahydrofuran / 1.) 65-70 deg C, 3 h; 2.) 20 deg C, 3 h 4: 1.) 2percent O3 in O2; 2.) sodium tetrahydroborate / 1.) cyclohexane, methanol; 2.) room temp., 15 h 5: 1.) isobutylmagnesium bromide; 2.) C5H5TiCl2 / 1.) diethyl ether, 0 deg C, 15 min; 2.) room temp., 1-1,5 h 6: 90 percent / pyridine View Scheme
参考文献
Chemistry of Natural Compounds, , vol. 23, # 3 p. 365 - 368
Khimiya Prirodnykh Soedinenii, , # 3 p. 440 - 444
