1: NaH / tetrahydrofuran; dimethylformamide / 1.) r.t., 25 min, 2.) r.t., overnight
2: 5percent aq. HCl / ethyl acetate / 5 h / 50 °C
View Scheme
参考文献
Brown, David S.; Elliott, Mark C.; Moody, Christopher J.; Mowlem, Timothy J.; Marino, Joseph P.; Padwa, Albert
Journal of Organic Chemistry, 1994 , vol. 59, # 9 p. 2447 - 2455
1: NaH / tetrahydrofuran; dimethylformamide / 1.) r.t., 30 min, 2.) r.t., 8 h
2: 5percent aq. HCl / ethyl acetate / 24 h / 50 °C
3: 78 percent / tetrahydrofuran / 3 h / Ambient temperature
4: Rh2(NHCOCF3)4 / benzene / 8 h / Ambient temperature
5: SiO2
View Scheme
参考文献
Brown, David S.; Elliott, Mark C.; Moody, Christopher J.; Mowlem, Timothy J.; Marino, Joseph P.; Padwa, Albert
Journal of Organic Chemistry, 1994 , vol. 59, # 9 p. 2447 - 2455
Medina-Ramos, Wilmarie; Mojica, Mike A.; Cope, Elizabeth D.; Hart, Ryan J.; Pollet, Pamela; Eckert, Charles A.; Liotta, Charles L.
Green Chemistry, 2014 , vol. 16, # 4 p. 2147 - 2155
1: water / 0.33 h / 150 °C / |Green chemistry
2: water / 150 °C / |Green chemistry
View Scheme
参考文献
Medina-Ramos, Wilmarie; Mojica, Mike A.; Cope, Elizabeth D.; Hart, Ryan J.; Pollet, Pamela; Eckert, Charles A.; Liotta, Charles L.
Green Chemistry, 2014 , vol. 16, # 4 p. 2147 - 2155
