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结构式
乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
2-碘噻吩
合成路线
(共 322 条)
3437-95-4
2-碘噻吩
+
195062-61-4
4-氯苯硼酸频哪醇酯
→
反应条件
40133-23-1
2-(4-氯苯基)噻吩
反应条件
potassium carbonate in methanol T=60°C; Suzuki-Miyaura Coupling; 1 h;
参考文献
Pandarus, Valerica; Desplantier-Giscard, Delphine; Gingras, Genevieve; Ciriminna, Rosaria; Demma Cara, Piera; Beland, Francois; Pagliaro, Mario
Tetrahedron Letters, 2013 , vol. 54, # 35 p. 4712 - 4716
3437-95-4
2-碘噻吩
+
109-79-5
丁硫醇
→
反应条件
3988-71-4
反应条件
in neat (no solvent) 0.25 h; Ambient temperature;
参考文献
Sang, Bok Lee; Jong-In, Hong
Tetrahedron Letters, 1995 , vol. 36, # 46 p. 8439 - 8442
3437-95-4
2-碘噻吩
+
629-05-0
1-辛炔
→
反应条件
391669-53-7
反应条件
copper(l) iodide; ethanolamine; triphenylphosphine; palladium on activated charcoal in water T=80°C; Sonogashira coupling; 8 h;
参考文献
Raju, Sirisilla; Kumar, P. Rajender; Mukkanti; Annamalai, Pazhanimuthu; Pal, Manojit
Bioorganic and Medicinal Chemistry Letters, 2006 , vol. 16, # 24 p. 6185 - 6189
3437-95-4
2-碘噻吩
→
反应条件
3988-99-6
反应条件
caesium carbonate; thiourea; copper(II) oxide in dimethyl sulfoxide T=20 - 110°C; Inert atmosphere;
参考文献
Reddy, K. Harsha Vardhan; Reddy, V. Prakash; Shankar; Madhav; Anil Kumar; Nageswar
Tetrahedron Letters, 2011 , vol. 52, # 21 p. 2679 - 2682
7774-74-5
+
3437-95-4
2-碘噻吩
→
反应条件
3988-99-6
反应条件
in neat (no solvent) 0.0833333 h; Ambient temperature;
参考文献
Sang, Bok Lee; Jong-In, Hong
Tetrahedron Letters, 1995 , vol. 36, # 46 p. 8439 - 8442
3437-95-4
2-碘噻吩
+
201230-82-2
+
1679-18-1
→
反应条件
4153-45-1
反应条件
potassium carbonate in methoxybenzene T=80°C; carbonylative Suzuki-Miyaura cross-coupling; P=760.051 Torr; 8 h;
参考文献
Cai, Mingzhong; Peng, Jian; Hao, Wenyan; Ding, Guodong
Green Chemistry, 2011 , vol. 13, # 1 p. 190 - 196
3437-95-4
2-碘噻吩
+
201230-82-2
→
反应条件
527-72-0
+
53439-38-6
反应条件
calcium hydroxide powder; water; dichlorobis(trimethylphosphine)palladium in isopropyl alcohol T=100°C; 12 h; P(CO) = 150 atm at room temperature;
参考文献
Kobayashi, Toshi-aki; Sakakura, Toshiyasu; Tanaka, Masato
Tetrahedron Letters, 1987 , vol. 28, # 24 p. 2721 - 2722
3437-95-4
2-碘噻吩
+
201230-82-2
+
5467-74-3
→
反应条件
4160-65-0
反应条件
tris-(dibenzylideneacetone)dipalladium(0); potassium carbonate in methoxybenzene T=100°C; Suzuki carbonylative coupling; P=760.051 Torr; 20 h; chemoselective reaction;
参考文献
Li, Hongling; Yang, Min; Qi, Yanxing; Xue, Jijun
European Journal of Organic Chemistry, 2011 , # 14 p. 2662 - 2667
3437-95-4
2-碘噻吩
+
2567-81-9
→
反应条件
56053-84-0
反应条件
palladium diacetate in 1-methyl-pyrrolidin-2-one T=20 - 140°C; 24 h; Inert atmosphere;
参考文献
Li, Yan; Chen, Huan-Huan; Wang, Chu-Fei; Xu, Xiao-Lan; Feng, Yi-Si
Tetrahedron Letters, 2012 , vol. 53, # 43 p. 5796 - 5799
3437-95-4
2-碘噻吩
+
13884-13-4
→
反应条件
55968-16-6
反应条件
tetrakis(triphenylphosphine) palladium(0); tert.-butyl lithium; zinc(II) chloride Yield given. Multistep reaction;
参考文献
Sakamoto, Takao; Kondo, Yoshinori; Takazawa, Nobuo; Yamanaka, Hiroshi
Journal of the Chemical Society - Perkin Transactions 1, 1996 , # 16 p. 1927 - 1934
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