反应条件
1.1: 98 percent / DIBAL-H / toluene / 0.08 h / -78 °C
2.1: 91 percent / Dess-Martin periodinane; NaHCO3 / CH2Cl2 / 1 h / 25 °C
3.1: BuLi / toluene; hexane / 0.08 h / -78 °C
4.1: 91.0 mg / Dess-Martin periodinane; NaHCO3 / CH2Cl2 / 1 h / 25 °C
5.1: 91 percent / t-BuOK / toluene; tetrahydrofuran / 2 h / 0 °C
6.1: CeCl3; t-BuLi / toluene; tetrahydrofuran; diethyl ether / 0.08 h / -78 °C
7.1: 93 percent / PPTS / 3.5 h / 25 °C
8.1: 2,6-lutidine / CH2Cl2 / 0.75 h / -20 °C
9.1: aq. HCl / acetone / 2 h / -15 - 0 °C
10.1: 40 percent / Ag2CO3-Celite / benzene / 2 h / 80 °C
11.1: PCl3; pyridine / 0.25 h / 25 °C
11.2: 1 h
12.1: 3.9 mg / aq. H2O2 / CH2Cl2; pyridine / 0.5 h
13.1: aq. HF / acetonitrile / 0.25 h / 25 °C
13.2: aq. HF; pyridine / acetonitrile / 168000 h
View Scheme
参考文献
Boger; Ichikawa; Zhong
Journal of the American Chemical Society, 2001 , vol. 123, # 18 p. 4161 - 4167
