3,5,5-三甲基-1-己醇合成路线 （共 22 条）
反应条件
1: phthalic anhydride; 2-methyl-propan-1-ol T=130°C; 1 h; 2: 3,5,5-trimethyl-1-hexanol; 2-methyl-propan-1-ol With tin oxide T=220°C; P=150.015 Torr; 7 h; Dean-Stark trap; Product distribution / selectivity;
参考文献
New Japan Chemical, Co., Ltd.
Patent: US2005/38283 A1, 2005 ;
Location in patent: Page/Page column 43-44 ;
反应条件
chromium(VI) oxide; acetic acid
参考文献
Bruner
Industrial and Engineering Chemistry, 1949 , vol. 41, p. 2861
反应条件
T=250°C; mit seiner Natriumverbindung;
参考文献
Bruner
Industrial and Engineering Chemistry, 1949 , vol. 41, p. 2861
反应条件
1: water; sulfuric acid; hydrobromic acid 2: magnesium; diethyl ether / Beim Behandeln der Reaktionsloesung mit Ammoniumchlorid in Wasser View Scheme
参考文献
Turner; Turner
Journal of the Chemical Society, 1952 , p. 1761
反应条件
trichlorophosphate
T=50°C; P=25 Torr;
参考文献
Goodrich Co.
Patent: US2650908 , 1951 ;
反应条件
1: chromium (VI)-oxide; acetic acid
2: phosphorus (V)-chloride
3: pyridine
View Scheme
参考文献
Turner; Turner
Journal of the Chemical Society, 1951 , p. 2543
反应条件
1: 2-methyl-propan-1-ol; 3a,4,7,7a-tetrahydro-1,3-isobenzofurandione T=130°C; 1 h;
2: 3,5,5-trimethyl-1-hexanol; 2-methyl-propan-1-ol With Tin Hydroxide
T=220°C; P=150.015 Torr; 7 h; Dean-Stark trap; Product distribution / selectivity;
参考文献
New Japan Chemical, Co., Ltd.
Patent: US2005/38283 A1, 2005 ;
Location in patent: Page/Page column 40 ;
反应条件
pyridine in diethyl ether
T=20°C; 2 h;
参考文献
Gimenez-Pedros, Marta; Aghmiz, Ali; Ruiz, Nuria; Masdeu-Bulto, Anna M.
European Journal of Inorganic Chemistry, 2006 , # 5 p. 1067 - 1075
反应条件
1: pyridine; thionyl chloride
2: aqueous ethanol
3: aq.-ethanolic NaOH-solution
4: diethyl ether
5: iodine / 200 °C
View Scheme
参考文献
Gutman; Hickinbottom
Journal of the Chemical Society, 1951 , p. 2064,2066
反应条件
pyridinium hydrobromide perbromide in water
T=20°C; 14 h;
参考文献
Sayama, Shinsei; Onami, Tetsuo
Synlett, 2004 , # 15 p. 2739 - 2745
