甲基7-(5-氧代-1-环戊烯-1-基)庚酸酯合成路线 （共 105 条）
反应条件
1: manganese triacetate (MTA) / 2 h / 60 °C
2: MeONa / methanol / 5 h / Ambient temperature
View Scheme
参考文献
Ogibin; Starostin; Aleksandrov; Pivnitsky; Nikishin
Synthesis, 1994 , # 9 p. 901 - 903
反应条件
1: tributyltin hydride, AIBN / benzene / 2 h / 80 °C
2: aq. HCl / methanol / 6 h / Ambient temperature
3: 70 percent / CH3ONa / methanol / 10 h / Ambient temperature
View Scheme
参考文献
Ono, Noboru; Fujii, Masayuki; Kaji, Aritsune
Synthesis, 1987 , # 6 p. 532 - 535
反应条件
1: 70 percent / pyridinium chlorochromate, A4 molecular sieves / CH2Cl2 / 24 h / Ambient temperature
2: 78 percent / AIBN, tri n-butyltin hydride / benzene / 5 h / Heating
3: 71 percent / boron trifluoride etherate, p-toluenesulfonic acid / acetone; H2O / Ambient temperature
4: 72 percent / sodium methoxide / methanol
View Scheme
参考文献
Rosini, Goffredo; Ballini, Roberto; Petrini, Marino; Sorrenti, Pietro
Tetrahedron, 1984 , vol. 40, # 19 p. 3809 - 3814
反应条件
1: 78 percent / AIBN, tri n-butyltin hydride / benzene / 5 h / Heating
2: 71 percent / boron trifluoride etherate, p-toluenesulfonic acid / acetone; H2O / Ambient temperature
3: 72 percent / sodium methoxide / methanol
View Scheme
参考文献
Rosini, Goffredo; Ballini, Roberto; Petrini, Marino; Sorrenti, Pietro
Tetrahedron, 1984 , vol. 40, # 19 p. 3809 - 3814
反应条件
1: 95 percent / O3 / methanol / -50 °C
2: 70 percent / CH3ONa / methanol
View Scheme
参考文献
Valcavi, Umberto; Farina, Paolo; Innocenti, Sergio; Marotta, Vittorio
Synthesis, 1983 , # 2 p. 124 - 125
反应条件
1: 60 percent / K2CO3 / Co2(CO)8 / 72 h / 40 °C
2: 1.) polyphosphoric acid, 2.) HCl / 1.) 100 deg C, 1 h, 2.) room temp., 1 d
View Scheme
参考文献
Dalcanale, Enrico; Foa, Marco
Synthesis, 1986 , # 6 p. 492 - 494
反应条件
1: 96 percent / 10percent aq. NaOH / 20 h / Heating
2: 90 percent / 98percent H2SO4 / 3 h / Ambient temperature
3: 95 percent / O3 / methanol / -50 °C
4: 70 percent / CH3ONa / methanol
View Scheme
参考文献
Valcavi, Umberto; Farina, Paolo; Innocenti, Sergio; Marotta, Vittorio
Synthesis, 1983 , # 2 p. 124 - 125
反应条件
1: N-chlorosuccinimide / CCl4 / 10 h / Ambient temperature
2: 89 percent / anhydrous ZnBr2 / CH2Cl2 / 2 h / Ambient temperature
3: 1.) m-chloroperbenzoic acid / 1.) CH2Cl2, 0 degC, 30 min., 2.) toluene, 100 degC, 4h
4: 62 percent / 6N hydrochloric acid / methanol / 8 h / Heating
View Scheme
参考文献
Ono, Noboru; Miyake, Hideyoshi; Kaji, Aritsume
Synthesis, 1981 , # 12 p. 1003 - 1004
反应条件
1: O3 / methanol; CHCl3
3: polyphosphoric acid
View Scheme
参考文献
Gokhale; Dalavoy; Prakasa Rao; et al.
Synthesis, 1974 , vol. No. 10, p. 718 - 719
反应条件
1: H2 / PtO2
2: CuCl, DCC
3: H2 / Pd-CaCO3
4: ZnCl2
5: (i) HgCl2, CdCO3, (ii) K2CO3, MeOH
View Scheme
参考文献
Ide,J. et al.
Bulletin of the Chemical Society of Japan, 1978 , vol. 51, # 3 p. 939 - 940
