in gas 1.) microwave discharge, nominal power 30 - 50 W, residence time 0.1 ms, p0(He) 350 Pa, 2.) liquid N2 cooled plate for scavenging of radical; Product distributionMechanismThermodynamic data;
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bis(cyclopentadienyl)titanium dichloride; dimethylaluminum chloride in benzene T=20°C; P=2280000 Torr; other pressures, reagents ratios; Product distribution;
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Enikolopyan, N. S.; Menchikova, G. N.; Grigoryan, E. A.
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in neat (no solvent) oxidn. of SO2 in a CH4-flame by atomic oxygen, chain mechanism discussed;;
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Dooley, A.; Whittingham, G.
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Gmelin Handbook: S: MVol.B1, 121, page 265 - 267
in neat (no solvent, gas phase)
methane oxidn. with (18)O2 in presence of LaMnO(3+x) under static conditions; working gas mixt.: Ar, CH4 and (18)O2; total initial pressure 150 Pa; heated above 735 K; monitored by mass spectrometry;
参考文献
Mazo; Kudryashov; Kemnitz
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Gmelin Handbook: B: B-Verb.9, 1.2.2.1, page 15 - 20
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Witz, S.; Shepherd, J. L.; Hormats, E. I.
Patent: US3329485 , 1967 ;
C.A., 1967 , vol. 67, p. 108741
