2-(2-氯苯基)-5,5-二甲基-1,3,2-二氧硼杂环己烷合成路线 （共 5 条）
反应条件
1: 2,2,6,6-tetramethylpiperidine; n-butyllithium / tetrahydrofuran / -78 - 20 °C 2: toluene / 20 °C View Scheme
参考文献
Kristensen, Jesper; Lysen, Morten; Vedso, Per; Begtrup, Mikael
Organic Letters, 2001 , vol. 3, # 10 p. 1435 - 1437
参考文献
Kristensen, Jesper; Lysen, Morten; Vedso, Per; Begtrup, Mikael
Organic Letters, 2001 , vol. 3, # 10 p. 1435 - 1437
反应条件
1,1'-bis-(diphenylphosphino)ferrocene; [1,3-bis(diphenylphosphino) propane] dichloronickel(II); triethylamine in toluene T=23 - 100°C; Inert atmosphere;
参考文献
Moldoveanu, Costel; Wilson, Daniela A.; Wilson, Christopher J.; Leowanawat, Pawaret; Resmerita, Ana-Maria; Liu, Chi; Rosen, Brad M.; Percec, Virgil
Journal of Organic Chemistry, 2010 , vol. 75, # 16 p. 5438 - 5452
反应条件
1: With potassium tert-butylate; silver(I) acetate; triphenylphosphine in tetrahydrofuran T=70°C; P=15201 Torr; 16 h; Inert atmosphereAutoclave; 2: With hydrogenchloride in tetrahydrofuran; water Inert atmosphere;
参考文献
Zhang, Xiao; Zhang, Wen-Zhen; Shi, Ling-Long; Guo, Chun-Xiao; Zhang, Ling-Ling; Lu, Xiao-Bing
Chemical Communications, 2012 , vol. 48, # 50 p. 6292 - 6294
反应条件
cesium fluoride; bis-triphenylphosphine-palladium(II) chloride in tetrahydrofuran
T=80°C; 16 h;
参考文献
Lysen, Morten; Kelleher, Susan; Begtrup, Mikael; Kristensen, Jesper Langgaard
Journal of Organic Chemistry, 2005 , vol. 70, # 13 p. 5342 - 5343
