2-乙炔-4,4,5,5-四甲基-[1,3,2]二噁硼烷合成路线 （共 17 条）
反应条件
in 1,3,5-trimethyl-benzene 16 h; RefluxInert atmosphere; regioselective reaction;
参考文献
Journal of the American Chemical Society, , vol. 131, p. 7762 - 7769
反应条件
in 1,3,5-trimethyl-benzene 16 h; Heating;
参考文献
Angewandte Chemie - International Edition, , vol. 46, # 45 p. 8656 - 8658
反应条件
in toluene T=110°C; 48 h; Inert atmosphere; regioselective reaction;
参考文献
Delaney, Patrick M.; Huang, Jianhui; Macdonald, Simon J. F.; Harrity, Joseph P. A.
Organic Letters, 2008 , vol. 10, # 5 p. 781 - 783
反应条件
CoCp(C2H4)2 in tetrahydrofuran
T=20°C; 1 h; Title compound not separated from byproducts.;
参考文献
Iannazzo, Laura; Vollhardt, K. Peter C.; Malacria, Max; Aubert, Corinne; Gandon, Vincent
European Journal of Organic Chemistry, 2011 , # 18 p. 3283 - 3292
反应条件
1.1: Schwartz's reagent / tetrahydrofuran / 1 h / 20 °C / |Inert atmosphere
1.2: 1 h / 20 °C / |Inert atmosphere
2.1: hydrogen; [Ir((S)-PPh2C6H4C3H3NOiPr)(COD)](tetrakis(3,5-di(trifluoromethyl)phenyl)borate) / dichloromethane / 18 h / 50 °C / 22502.3 Torr
View Scheme
参考文献
Roseblade, Stephen J.; Smilovic, Ivana Gazic; Casar, Zdenko
Tetrahedron, 2014 , vol. 70, # 16 p. 2654 - 2660
反应条件
1.1: Schwartz's reagent / tetrahydrofuran / 1 h / 20 °C / |Inert atmosphere
1.2: 1 h / 20 °C / |Inert atmosphere
2.1: hydrogen; (C5H2N(C6H5))CH2CH2CH(O)P(C(CH3)3)2Ir(C8H12)(1+)*B(C8H3F6)4(1-)=(C5H2N(C6H5))CH2CH2CH(O)P(C(CH3)3)2Ir(C8H12)B(C8H3F6)4 / dichloromethane / 18 h / 50 °C / 22502.3 Torr
View Scheme
参考文献
Roseblade, Stephen J.; Smilovic, Ivana Gazic; Casar, Zdenko
Tetrahedron, 2014 , vol. 70, # 16 p. 2654 - 2660
反应条件
in xylene
16 h; Heating;
参考文献
Helm, Matthew D.; Plant, Andrew; Harrity, Joseph P. A.
Organic and Biomolecular Chemistry, 2006 , vol. 4, # 23 p. 4278 - 4280
