1: PTAS With tetrabutyl ammonium fluoride in tetrahydrofuran; water T=20°C; 1 h; 2: 1-chloro-2-fluorobenzene With 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl; bis(η3-allyl-μ-chloropalladium(II)) in tetrahydrofuran; water T=80°C; 3 h;
1: With tri-isopropoxy-borane; sec.-butyllithium in tetrahydrofuran; hexane; cyclohexane T=-78°C; 1 h; 2: With tri-isopropoxy-borane in tetrahydrofuran; hexane; cyclohexane T=-78 - 20°C; 3: With hydrogenchloride in tetrahydrofuran; hexane; cyclohexane; water pH=1;
lt;(η-C6H6)(η-C5EtMe4)Rhgt;(2+)*lt;PF6(1-)gt;2 in nitromethane T=80°C; 96 h; other concentration of catalyst, other temperature, other time; Product distributionMechanism;
参考文献
Goryunov, L. I.; Litvak, V. V.; Shteingarts, V. D.
Journal of Organic Chemistry USSR (English Translation), 1987 , vol. 23, # 6 p. 1112 - 1118
Zhurnal Organicheskoi Khimii, 1987 , vol. 23, # 6 p. 1230 - 1237
