反应条件
1: 5-bromo-5'-ethyl-2,2'-bithiophene With magnesium in diethyl ether T=35°C; Inert atmosphereReflux; 2: 2,5-dibromothiophene With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride in diethyl ether T=20°C; Kumada coupling reaction; Inert atmosphereCooling with ice;
参考文献
Ponomarenko, Sergei A.; Borshchev, Oleg V.; Meyer-Friedrichsen, Timo; Pleshkova, Alexandra P.; Setayesh, Sepas; Smits, Edsger C. P.; Mathijssen, Simon G. J.; De Leeuw, Dago M.; Kirchmeyer, Stephan; Muzafarov, Aziz M.
Organometallics, 2010 , vol. 29, # 19 p. 4213 - 4226