2,6-二乙基-4-甲基苯酚合成路线 （共 7 条）
反应条件
ethanol; nickel T=85 - 135°C; Hydrogenation;
参考文献
Ungnade; McLaren
Journal of the American Chemical Society, 1944 , vol. 66, p. 118,119
反应条件
Ph2P(OPh); [rhodium(I)chloride(triphenylphosphine)3] in toluene T=120°C; P=22502.3 Torr; 15 h; Product distribution; Further Variations:Reagents;
参考文献
Carrion, M. Carmen; Cole-Hamilton, David J.
Chemical Communications, 2006 , # 43 p. 4527 - 4529
反应条件
1: potassium hydroxide / 1,4-dioxane / 0.6 h / 65 °C 2: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine / 37 h / |Inert atmosphere; |Reflux 3: potassium carbonate / methanol / 20 °C 4: acetic acid; palladium 10 on activated carbon; sodium tetrahydroborate / isopropyl alcohol / 1.5 h / 20 °C 5: boron tribromide / dichloromethane / 18.5 h / 0 - 20 °C View Scheme
参考文献
Zhao, Wenjun; Huang, Li; Guan, Yong; Wulff, William D.
Angewandte Chemie - International Edition, 2014 , vol. 53, # 13 p. 3436 - 3441
Angew. Chem., 2014 , vol. 126, # 13 p. 3504 - 3509,6
反应条件
1: bis-triphenylphosphine-palladium(II) chloride; copper(l) iodide; triethylamine / 37 h / |Inert atmosphere; |Reflux 2: potassium carbonate / methanol / 20 °C 3: acetic acid; palladium 10 on activated carbon; sodium tetrahydroborate / isopropyl alcohol / 1.5 h / 20 °C 4: boron tribromide / dichloromethane / 18.5 h / 0 - 20 °C View Scheme
参考文献
Zhao, Wenjun; Huang, Li; Guan, Yong; Wulff, William D.
Angewandte Chemie - International Edition, 2014 , vol. 53, # 13 p. 3436 - 3441
Angew. Chem., 2014 , vol. 126, # 13 p. 3504 - 3509,6
反应条件
aluminium tris(p-methylphenoxide) T=320 - 340°C;
参考文献
Stroh et al.
Angewandte Chemie, 1957 , vol. 69, p. 699,700
反应条件
T=85 - 135°C; unter Druck.Hydrogenation;
参考文献
Ungnade; McLaren
Journal of the American Chemical Society, 1944 , vol. 66, p. 118,119
反应条件
hydrogen; iron-aluminum catalyst T=340°C; further temperatures; Product distribution;
参考文献
Agaev; Shakhtakhtinskaya; Eminov; Guliev
Russian Journal of Applied Chemistry, 1998 , vol. 71, # 4 p. 651 - 653
