Alpha-正丁基苯乙腈合成路线 （共 19 条）
反应条件
sodium hydroxide in dichloromethane T=20°C; 1 h;
参考文献
Badet, Bernard; Julia, Marc; Lefebvre, Christian
Bulletin de la Societe Chimique de France, 1984 , vol. 2, # 11-12 p. 431 - 434
反应条件
1: potassium tert-butylate / ethanol; water / Inert atmosphere; Heating 2: bis(η3-allyl-μ-chloropalladium(II)); 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene / 1,3,5-trimethyl-benzene / 10.17 h / 20 - 140 °C / Inert atmosphere; Sealed tube View Scheme
参考文献
Shang, Rui; Ji, Dong-Sheng; Chu, Ling; Fu, Yao; Liu, Lei
Angewandte Chemie - International Edition, 2011 , vol. 50, # 19 p. 4470 - 4474
反应条件
sodium hydroxide; sulfur dioxide 24 h; Ambient temperature;
参考文献
Furukawa, Naomichi; Ogawa, Satoshi; Kawai, Tsutomu; Kishimoto, Keiko; Fujihara, Hisashi; Oae, Shigeru
Heterocycles, 1982 , vol. 19, # 11 p. 2041 - 2046
反应条件
acetonitrile(.eta.5-dimethylaminocyclopenyadienyl)bis(triphenylphosphine)ruthenium(II) tetrafluoroborate; 1,8-diazabicyclo[5.4.0]undec-7-ene T=120°C; 48 h; Inert atmosphere;
参考文献
Cheung, Hung Wai; Li, Juan; Zheng, Wenxu; Zhou, Zhongyuan; Chiu, Yu Hin; Lin, Zhenyang; Lau, Chak Po
Dalton Transactions, 2010 , vol. 39, # 1 p. 265 - 274
反应条件
copper(l) iodide; sodium hydride 1.) HMPA, room temperature, 0.5 h, 2.) 170 deg C, 5 h, then 200 deg C, overnight; Yield given. Multistep reaction;
参考文献
Suzuki, Hitomi; Watanabe, Kazue; Qui, Yi
Chemistry Letters, 1985 , p. 1779 - 1780
参考文献
CIBA
Patent: US2858315 , 1957 ;
反应条件
in ethylene glycol dimethyl ether T=25°C; The rate constants for the free carbanions and the ion pairs were calculated; Rate constant;
参考文献
Solov'yanov, A. A.; Beletskaya, I. P.; Reutov, O. A.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 1608 - 1611
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 9 p. 1840 - 1843
反应条件
in ethylene glycol dimethyl ether T=25°C; The rate constants for the free carbanions and the ion pairs were calculated; Rate constant;
参考文献
Solov'yanov, A. A.; Beletskaya, I. P.; Reutov, O. A.
Journal of Organic Chemistry USSR (English Translation), 1983 , vol. 19, p. 1608 - 1611
Zhurnal Organicheskoi Khimii, 1983 , vol. 19, # 9 p. 1840 - 1843
反应条件
(i) nBuLi, iPr2NH, THF, hexane, (ii) O2, (iii) /BRN= 605303/; Multistep reaction;
参考文献
Freerksen; Pabst; Raggio; Sherman; Wroble; Watt
Journal of the American Chemical Society, 1977 , vol. 99, # 5 p. 1536 - 1542
