3,5-二乙酰氧基苯乙酮合成路线 （共 12 条）
反应条件
hydrogen; Ni-alloy Degussa B 113 Z in ethyl acetate
T=70°C; P=1500.15 Torr; 20 h; Autoclave; Product distribution / selectivity;
参考文献
DSM IP ASSETS B.V.; BONRATH, Werner; LETINOIS, Ulla; HUGENTOBLER, Max; KARGE, Reinhard; LEHMANN, Hajo
Patent: WO2010/79123 A2, 2010 ;
Location in patent: Page/Page column 3 ;
反应条件
1: bromine; acetic acid / 1 h / 20 °C
2: sodium chloride / acetonitrile; water / 2.5 h / |Reflux
3: Candida antarctica lipase B; water / toluene; aq. phosphate buffer / 15.5 h / 50 °C / pH 7 / |Inert atmosphere; |Enzymatic reaction
View Scheme
参考文献
Taketomi, Shohei; Asano, Masayoshi; Higashi, Toshinori; Shoji, Mitsuru; Sugai, Takeshi
Journal of Molecular Catalysis B: Enzymatic, 2012 , vol. 84, p. 83 - 88
