二(1,5-环辛二烯)四氟硼酸铑(I)合成路线 （共 5 条）
反应条件
in dichloromethane T=25°C;
参考文献
Aydemir, Murat; Meric, Nermin; Kayan, Cezmi; Ok, Fatih; Baysal, Akin
Inorganica Chimica Acta, 2013 , vol. 398, p. 1 - 10
反应条件
1: in tetrahydrofuran 2: With tetrafluoroboric acid in tetrahydrofuran; diethyl ether T=50°C; Product distribution / selectivity;
参考文献
WO2010/1173 A1, ;
Page/Page column 14 ;
反应条件
in chloroform-d1 byproducts: acetonitrile; gradual addn. of soln. of Rh(COD)(MeCN)2BF4 in CDCl3 to COD; monitoring by NMR;
参考文献
Organometallics, , vol. 30, # 22 p. 6233 - 6240
反应条件
in dichloromethane; water 4 equiv of diopium, CH2Cl2-H2O, slight excess of NH4BF4, stirring for 2 h at room temp. (N2); the organic phase was sepd., concd.;
参考文献
Journal of Organometallic Chemistry, , vol. 654, # 1-2 p. 180 - 186
反应条件
(N2); treatment of rhodium compd. with silver compd. in mixt. of CH2Cl2 and acetone, addn. of diene deriv.;
参考文献
Organic and Biomolecular Chemistry, , vol. 5, # 20 p. 3340 - 3346
