(Z)-5-十四碳烯-1-醇乙酸酯合成路线 （共 19 条）
反应条件
pyridine in benzene T=20°C;
参考文献
Kovalev, B. G.; Dzhumakulov, T.; Abduvakhabov, A. A.; Sadykov, A. S.
Doklady Chemistry, 1987 , vol. 297, # 12 p. 544 - 548
Dokl. Akad. Nauk SSSR Ser. Khim., 1987 , vol. 297, # 6 p. 1381 - 1386
参考文献
Bestmann, H. J.; Brosche, T.; Koschatzky, K. H.; Michaelis, K.; Platz, H.; et. al.
Tetrahedron Letters, 1980 , vol. 21, p. 747 - 750
反应条件
hydrogen; Lindlar's catalyst in ethyl acetate
参考文献
Garanti,L. et al.
Gazzetta Chimica Italiana, 1976 , vol. 106, p. 187 - 196
反应条件
1: (i) NaNH2, liq. NH3, Fe(NO3)3, (ii) NaI, (iii) /BRN= 3595636/ 2: H2 / Lindlar catalyst / ethyl acetate View Scheme
参考文献
Garanti,L. et al.
Gazzetta Chimica Italiana, 1976 , vol. 106, p. 187 - 196
反应条件
1: (i) NaNH2, liq. NH3, Fe(NO3)3, (ii) NaI, (iii) /BRN= 3595636/ 2: H2 / Lindlar catalyst / ethyl acetate View Scheme
参考文献
Garanti,L. et al.
Gazzetta Chimica Italiana, 1976 , vol. 106, p. 187 - 196
反应条件
1: 1.) sodiobis(trimethylsilyl)amide / 1.) THF, 50-55 deg C, 60 min, 2.) -78 deg C, 30 min; 20 deg C, 12 h 2: 53 percent / HCl / H2O; acetone / 20 °C 3: 91 percent / LiAlH4 / diethyl ether / 20 °C 4: 87 percent / pyridine / benzene / 20 °C View Scheme
参考文献
Kovalev, B. G.; Dzhumakulov, T.; Abduvakhabov, A. A.; Sadykov, A. S.
Doklady Chemistry, 1987 , vol. 297, # 12 p. 544 - 548
Dokl. Akad. Nauk SSSR Ser. Khim., 1987 , vol. 297, # 6 p. 1381 - 1386
反应条件
1: 1.) sodiobis(trimethylsilyl)amide / 1.) THF, 50-55 deg C, 60 min, 2.) -78 deg C, 30 min; 20 deg C, 12 h 2: 53 percent / HCl / H2O; acetone / 20 °C 3: 91 percent / LiAlH4 / diethyl ether / 20 °C 4: 87 percent / pyridine / benzene / 20 °C View Scheme
参考文献
Kovalev, B. G.; Dzhumakulov, T.; Abduvakhabov, A. A.; Sadykov, A. S.
Doklady Chemistry, 1987 , vol. 297, # 12 p. 544 - 548
Dokl. Akad. Nauk SSSR Ser. Khim., 1987 , vol. 297, # 6 p. 1381 - 1386
反应条件
1: 91 percent / LiAlH4 / diethyl ether / 20 °C 2: 87 percent / pyridine / benzene / 20 °C View Scheme
参考文献
Kovalev, B. G.; Dzhumakulov, T.; Abduvakhabov, A. A.; Sadykov, A. S.
Doklady Chemistry, 1987 , vol. 297, # 12 p. 544 - 548
Dokl. Akad. Nauk SSSR Ser. Khim., 1987 , vol. 297, # 6 p. 1381 - 1386
反应条件
1: 53 percent / HCl / H2O; acetone / 20 °C 2: 91 percent / LiAlH4 / diethyl ether / 20 °C 3: 87 percent / pyridine / benzene / 20 °C View Scheme
参考文献
Kovalev, B. G.; Dzhumakulov, T.; Abduvakhabov, A. A.; Sadykov, A. S.
Doklady Chemistry, 1987 , vol. 297, # 12 p. 544 - 548
Dokl. Akad. Nauk SSSR Ser. Khim., 1987 , vol. 297, # 6 p. 1381 - 1386
反应条件
1: 90 percent / lithium aluminium hydride / diethyl ether / 3 h / Ambient temperature 2: 74 percent / pyridine / 24 h / Ambient temperature View Scheme
参考文献
Kelkar, S. V.; Reddy, G. Bhaskar; Kulkarni, G. H.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1989 , vol. 28, # 1-11 p. 980 - 981
