6-羟基-2,2’,3,4,4’-五溴联苯醚合成路线 （共 4 条）
反应条件
boron tribromide in dichloromethane T=50°C; 36 h;
参考文献
Marsh, Goeran; Stenutz, Roland; Bergman, Ake
European Journal of Organic Chemistry, 2003 , # 14 p. 2566 - 2576
反应条件
1: 59 percent / 18-crown-6; K2CO3 / N,N-dimethyl-acetamide / 1 h / 80 °C 2: 94 percent / boron tribromide / CH2Cl2 / 36 h / 50 °C View Scheme
参考文献
Marsh, Goeran; Stenutz, Roland; Bergman, Ake
European Journal of Organic Chemistry, 2003 , # 14 p. 2566 - 2576
反应条件
1: 95 percent / bromine / acetic acid / 20 - 35 °C 2: 59 percent / 18-crown-6; K2CO3 / N,N-dimethyl-acetamide / 1 h / 80 °C 3: 94 percent / boron tribromide / CH2Cl2 / 36 h / 50 °C View Scheme
参考文献
Marsh, Goeran; Stenutz, Roland; Bergman, Ake
European Journal of Organic Chemistry, 2003 , # 14 p. 2566 - 2576
反应条件
1: K2CO3 / acetone / 12 h / 80 °C
2: H2 / 10percent Pd-C / methanol / 25 °C
View Scheme
参考文献
Carte, Brad; Faulkner, D. John
Tetrahedron, 1981 , vol. 37, p. 2335 - 2340
