in water byproducts: KCl; (inert atm.); addn. of diethylsulfide to aq. soln. of platinum compd., stirring for 24 h; evapn. at 25°C in vac., extn. (hot benzene), filtration, concg., cooling to 0°C, filtration, washing with hexane, NMR;
参考文献
De Crisci, Antonio G.; Lough, Alan J.; Multani, Kanwarpal; Fekl, Ulrich
Organometallics, 2008 , vol. 27, # 8 p. 1765 - 1779
in water shaking of a soln. of K2(PtCl4) in H2O with S(C2H5)2; sucking off;; washing with H2O; recrystallization in alcohol for 1 time and 2-3 times in ether;;
参考文献
Blomstrand, C. W.
Journal fuer Praktische Chemie (Leipzig), 1888 , vol. 38, p. 345 - 365
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Gmelin Handbook: Pt: MVol.D, 137, page 307 - 309
sulfuryl dichloride; triethylamine 1.) dichloromethane, -40 deg C, 20 min; 2.) dichloromethane, from -30 deg C allowed to warm to r.t.; Yield given. Multistep reaction;
参考文献
Sato, Kikumasa; Inoue, Seiichi; Miyamoto, Osamu; Ikeda, Hiroshi; Ota, Tomomi
Bulletin of the Chemical Society of Japan, 1987 , vol. 60, # 11 p. 4184 - 4186
T=580 - 610°C; 0.0236111 h; pyrolysis of dimethyl sulfide and "disulfide oil", var. reaction conditions; MechanismProduct distribution;
参考文献
Deryagina, E. N.; Sukhomazova, E. N.; Russavskaya, N. V.; Levanova, E. P.; Voronkov, M. G.
Russian Journal of Organic Chemistry, 1993 , vol. 29, # 11.2 p. 1924 - 1925
Zhurnal Organicheskoi Khimii, 1993 , vol. 29, # 11 p. 2315 - 2316
