(E)-辛-3-烯酸甲酯合成路线 （共 16 条）
反应条件
toluene-4-sulfonic acid 24 h; Ambient temperature;
参考文献
Odinokov, V. N.; Ishmuratov, G. Yu.; Ladenkova, I. M.; Botsman, L. P.; Kargapol'tseva, T. A.; Tolstikov, G. A.
Chemistry of Natural Compounds, 1991 , vol. 27, # 5 p. 621 - 623
Khimiya Prirodnykh Soedinenii, 1991 , # 5 p. 704 - 707
反应条件
1: 95 percent / H2 / 10percent Pd/C / methanol / 24 h / 25 °C 2: 1.) cupric acetate, pyridine, 2.) lead tetraacetate / 1.) benzene, 25 deg C, 45 min, 2.) benzene, reflux, 3 h View Scheme
参考文献
Dhokte; Rao
Indian Journal of Chemistry - Section B Organic Chemistry Including Medicinal Chemistry, 1990 , vol. 29, # 12 p. 1089 - 1091
反应条件
1,8-diazabicyclo[5.4.0]undec-7-ene in N,N-dimethyl-formamide T=80°C; 3 h; Yield given;
参考文献
Mohan, H Rama; Rao, A S
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1992 , vol. 31, # 10 p. 698 - 700
反应条件
1: 75 percent / aq. NaOH, trioctylmethylammonium chloride / toluene / 48 h / Ambient temperature 2: 80 percent / H2O2 / acetic acid / 24 h 3: 51 percent / conc. hydrochloric acid / methanol / 6 h / Heating View Scheme
参考文献
Ogura, Katsuyuki; Watanabe, Jun-ichi; Iida, Hirotada
Tetrahedron Letters, 1981 , vol. 22, # 45 p. 4499 - 4502
反应条件
1: 80 percent / H2O2 / acetic acid / 24 h 2: 51 percent / conc. hydrochloric acid / methanol / 6 h / Heating View Scheme
参考文献
Ogura, Katsuyuki; Watanabe, Jun-ichi; Iida, Hirotada
Tetrahedron Letters, 1981 , vol. 22, # 45 p. 4499 - 4502
反应条件
1: 1.) NaH / 1.) 70 deg C, 45 min, 2.) THF, 25 deg C, 4 h 2: Ac2O / 0.75 h / 140 °C 3: aq. NaOH / methanol / 2 h / Heating 4: diethyl ether 5: phosphorous tribromide / 1.) 25 deg C, 12 h, 2.) 80 deg C, 1 h 6: NaI / dimethylformamide / 3 h / 50 °C 7: 1,8-diazabicyclo<5.4.0>undec-7-ene (DBU) / dimethylformamide / 3 h / 80 °C View Scheme
参考文献
Mohan, H Rama; Rao, A S
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1992 , vol. 31, # 10 p. 698 - 700
反应条件
1: diethyl ether 2: phosphorous tribromide / 1.) 25 deg C, 12 h, 2.) 80 deg C, 1 h 3: NaI / dimethylformamide / 3 h / 50 °C 4: 1,8-diazabicyclo<5.4.0>undec-7-ene (DBU) / dimethylformamide / 3 h / 80 °C View Scheme
参考文献
Mohan, H Rama; Rao, A S
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1992 , vol. 31, # 10 p. 698 - 700
反应条件
1: phosphorous tribromide / 1.) 25 deg C, 12 h, 2.) 80 deg C, 1 h 2: NaI / dimethylformamide / 3 h / 50 °C 3: 1,8-diazabicyclo<5.4.0>undec-7-ene (DBU) / dimethylformamide / 3 h / 80 °C View Scheme
参考文献
Mohan, H Rama; Rao, A S
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1992 , vol. 31, # 10 p. 698 - 700
反应条件
1: NaI / dimethylformamide / 3 h / 50 °C 2: 1,8-diazabicyclo<5.4.0>undec-7-ene (DBU) / dimethylformamide / 3 h / 80 °C View Scheme
参考文献
Mohan, H Rama; Rao, A S
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1992 , vol. 31, # 10 p. 698 - 700
反应条件
1: Ac2O / 0.75 h / 140 °C 2: aq. NaOH / methanol / 2 h / Heating 3: diethyl ether 4: phosphorous tribromide / 1.) 25 deg C, 12 h, 2.) 80 deg C, 1 h 5: NaI / dimethylformamide / 3 h / 50 °C 6: 1,8-diazabicyclo<5.4.0>undec-7-ene (DBU) / dimethylformamide / 3 h / 80 °C View Scheme
参考文献
Mohan, H Rama; Rao, A S
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1992 , vol. 31, # 10 p. 698 - 700
