3,4,5-三甲氧基-2-溴苯甲醛合成路线 （共 21 条）
反应条件
bromine in chloroform; water Heating / reflux;
参考文献
Labruere, Raphael; Helissey, Philippe; Desbene-Finck, Stephanie; Giorgi-Renault, Sylviane
Letters in Organic Chemistry, 2012 , vol. 9, # 8 p. 568 - 571,4
反应条件
manganese(IV) oxide in benzene
参考文献
Ziegler, Frederick E.; Chliwner, Irene; Fowler, Kerry W.; Kanfer, Sheldon J.; Kuo, Stephen J.; Sinha, Nanda D.
Journal of the American Chemical Society, 1980 , vol. 102, # 2 p. 790 - 798
反应条件
1: 2-bromo-3,5-dihydroxy-4-methoxybenzaldehyde With sodium hydride in N,N-dimethyl-formamide T=20°C; 0.5 h; 2: methyl iodide in N,N-dimethyl-formamide T=50°C; 7.5 h; Further stages.;
参考文献
Radix, Sylvie; Barret, Roland
Tetrahedron, 2007 , vol. 63, # 50 p. 12379 - 12387
反应条件
1: 80 percent / N-bromosuccinimide / CHCl3 / 3 h / Heating 2: 85 percent / MnO2 / benzene View Scheme
参考文献
Ziegler, Frederick E.; Chliwner, Irene; Fowler, Kerry W.; Kanfer, Sheldon J.; Kuo, Stephen J.; Sinha, Nanda D.
Journal of the American Chemical Society, 1980 , vol. 102, # 2 p. 790 - 798
参考文献
Gutsche et al.
Journal of the American Chemical Society, 1958 , vol. 80, p. 5756,5766
反应条件
1: SOCl2 2: palladium/BaSO4 View Scheme
参考文献
Gutsche et al.
Journal of the American Chemical Society, 1958 , vol. 80, p. 5756,5766
反应条件
N-bromosuccinmide in tetrachloromethane Bromination; 12 h; Irradiation;
参考文献
Sarma, Jagarlapudi A.R.P.; Nagaraju, Akula; Majumdar, Kanak K.; Samuel, Purnima M.; Das, Indira; Roy, Sujit; McGhie, Alistair J.
Journal of the Chemical Society. Perkin Transactions 2, 2000 , # 6 p. 1119 - 1123
反应条件
copper T=250°C; 0.25 h;
参考文献
Tetrahedron, , vol. 38, # 16 p. 2569 - 2580
反应条件
NiCl2((PPh3)P)2; tetra-(n-butyl)ammonium iodide; (S)-(+)-(3,5-dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)diethylamine; zinc in N,N-dimethyl acetamide T=45°C; Ullmann reaction; 4 h; Inert atmosphere; optical yield given as percent eeenantioselective reaction;
参考文献
Chen, Wen-Wen; Zhao, Qian; Xu, Ming-Hua; Lin, Guo-Qiang
Organic Letters, 2010 , vol. 12, # 5 p. 1072 - 1075
反应条件
sodium tetrahydroborate in ethanol
T=0 - 20°C;
参考文献
Kumar, Sarvesh; Peruncheralathan, Saravanan; Ila, Hiriyakkanavar; Junjappa, Hiriyakkanavar
Organic Letters, 2008 , vol. 10, # 5 p. 965 - 968
