3,4,5-三甲氧基-2-溴苯甲醛合成路线 （共 21 条）
参考文献
Broady, Simon D.; Golden, Michael D.; Leonard, John; Muir, James C.; Maudet, Mickael
Tetrahedron Letters, 2007 , vol. 48, # 26 p. 4627 - 4630
反应条件
1: Methyltriphenylphosphonium bromide With n-butyllithium in tetrahydrofuran; hexane
T=20°C; 0.25 h;
2: bromo-2 trimethoxy-3,4,5 benzaldehyde in tetrahydrofuran; hexane
T=20°C; Wittig reaction; 3 h;
参考文献
Appukkuttan, Prasad; Dehaen, Wim; Van Der Eycken, Erik
Organic Letters, 2005 , vol. 7, # 13 p. 2723 - 2726
反应条件
1: triphenyl-methyl-phosphonium iodide With n-butyllithium in tetrahydrofuran; hexane
T=0°C; 0.5 h;
2: bromo-2 trimethoxy-3,4,5 benzaldehyde in tetrahydrofuran; hexane
T=0 - 25°C;
参考文献
Reddy, R.Santhosh; Kiran, I. N. Chaithanya; Sudalai, Arumugam
Organic and Biomolecular Chemistry, 2012 , vol. 10, # 18 p. 3655 - 3661
反应条件
copper in N,N-dimethyl-formamide
Ullmann reaction; 18 h; Heating;
参考文献
Molander, Gary A.; George, Kelly M.; Monovich, Lauren G.
Journal of Organic Chemistry, 2003 , vol. 68, # 25 p. 9533 - 9540
反应条件
copper in N,N-dimethyl-formamide
T=165°C; Ullmann Reaction; 3 h;
参考文献
THE UNIVERSITY OF MANCHESTER
Patent: WO2008/75048 A2, 2008 ;
Location in patent: Page/Page column 68 ;
反应条件
copper
T=250°C; 0.25 h;
参考文献
Brown, Eric; Robin, Jean-Pierre; Dhal, Robert
Tetrahedron, 1982 , vol. 38, # 16 p. 2569 - 2580
反应条件
copper
T=250°C; 0.25 h;
参考文献
Brown, Eric; Robin, Jean-Pierre; Dhal, Robert
Tetrahedron, 1982 , vol. 38, # 16 p. 2569 - 2580
反应条件
copper in N,N-dimethyl-formamide
T=165°C; Ullmann reaction; 3 h;
参考文献
Edwards, David J.; Hadfield, John A.; Wallace, Timothy W.; Ducki, Sylvie
Organic and Biomolecular Chemistry, 2011 , vol. 9, # 1 p. 219 - 231
反应条件
copper
T=210°C; 0.333333 h;
参考文献
Brown, Eric; Robin, Jean-Pierre; Dhal, Robert
Tetrahedron, 1982 , vol. 38, # 16 p. 2569 - 2580
反应条件
copper
T=180°C; 0.333333 h;
参考文献
Brown, Eric; Robin, Jean-Pierre; Dhal, Robert
Tetrahedron, 1982 , vol. 38, # 16 p. 2569 - 2580
