2-甲基-2-苯丙基氯化镁合成路线 （共 22 条）
反应条件
1: diethyl ether 2: not given View Scheme
参考文献
Journal of the American Chemical Society, , vol. 111, # 8 p. 2883 - 2891
反应条件
in diethyl ether; toluene 1.44M Et2O soln. of NeophMgCl (1.7-2.05 equiv.) dropwise with stirring added to toluene soln. of SnCl4 (1 equiv.) under N2 at room temp., heatedat reflux for 3 h, left at room temp. for 12 h; aq. satd. soln. NH4Cl added, organic layer separated, aq. layer extracted with Et2O, combined organic extracts dried over MgSO4, solvent removedunder vac., recrystd. from n-heptane; ratio of Nph3SnCl/Nph2SnCl2 was 6 0/40-24.5/75.5, NMR;
参考文献
Zuniga, Adriana E.; Fidelibus, Pablo M.; Mandolesi, Sandra D.; Podesta, Julio C.
Journal of Organometallic Chemistry, 2011 , vol. 696, # 8 p. 1547 - 1555
反应条件
in diethyl ether; benzene final reflux in benzene;
参考文献
Zimmer,H. et al.
Journal of Organic Chemistry, 1966 , vol. 31, p. 3857 - 3860
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Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.13, page 122 - 129
反应条件
1: (2-methyl-2-phenylpropyl)MgCl With zinc(II) chloride in tetrahydrofuran T=20°C; 2: 1-tributylstannyl-2-phenylacetylene With bis(dibenzylideneacetone)-palladium(0) in dichloromethane Further stages.;
参考文献
Synthesis, , # 4 p. 649 - 654
反应条件
diethyl ether; ethyl toluene-4-sulfonate
参考文献
Pines et al.
Journal of the American Chemical Society, 1953 , vol. 75, p. 2311,2314
参考文献
Petrow et al.
Zhurnal Obshchei Khimii, 1958 , vol. 28, p. 2315,2317, 2319; engl. Ausg. S. 2353, 2355,2356
反应条件
2-bromo-1,2-diphenylethan-1-one; zinc dibromide; ((S)-2,2′-bis(diphenylphosphino)-1,1′-binaphthyl)PdCl2*2THF
T=20°C;
参考文献
Zhao, Yingsheng; Wang, Haibo; Hou, Xiaohui; Hu, Yanhe; Lei, Aiwen; Zhang, Heng; Zhu, Lizheng
Journal of the American Chemical Society, 2006 , vol. 128, # 47 p. 15048 - 15049
参考文献
Petrow et al.
Zhurnal Obshchei Khimii, 1958 , vol. 28, p. 2315,2317, 2319; engl. Ausg. S. 2353, 2355,2356
参考文献
Petrow et al.
Zhurnal Obshchei Khimii, 1958 , vol. 28, p. 2315,2317, 2319; engl. Ausg. S. 2353, 2355,2356
参考文献
Petrow et al.
Zhurnal Obshchei Khimii, 1958 , vol. 28, p. 2315,2317, 2319; engl. Ausg. S. 2353, 2355,2356
