in neat (no solvent) byproducts: CsSbF6, F2N2; not isolated, detected by FT-IR;
参考文献
Netzloff, Heather M.; Gordon, Mark S.; Christe, Karl; Wilson, William W.; Vij, Ashwani; Vij, Vandana; Boatz, Jerry A.
Journal of Physical Chemistry A, 2003 , vol. 107, # 34 p. 6638 - 6647
in neat (no solvent) NO added to Sb deriv. at -196°C (dry box, vacuum line) and warm slowly to room temp.; volatiles pumped off; detd. by vibrational spectroscopy;
参考文献
Vij; Wilson; Tham; Sheehy; Christe
Journal of the American Chemical Society, 2001 , vol. 123, # 26 p. 6308 - 6313
in neat (no solvent) NO2 added to Sb deriv. at -196°C (dry box, vacuum line) and warm slowly to room temp.; volatiles pumped off; detd. by vibrational spectroscopy;
参考文献
Vij; Wilson; Tham; Sheehy; Christe
Journal of the American Chemical Society, 2001 , vol. 123, # 26 p. 6308 - 6313
in sulfur dioxide
byproducts: N2; liq. SO2 wasadded to mixt. of N5SbF6 and CsN3 in drybox at -196°C; mixt. was warmed to -64°C; volatiles removed at -64°C; pumped at room temp.;
参考文献
Dixon, David A.; Feller, David; Christe, Karl O.; Wilson, William W.; Vij, Ashwani; Vij, Vandana; Jenkins, H. Donald Brooke; Olson, Ryan M.; Gordon, Mark S.
Journal of the American Chemical Society, 2004 , vol. 126, # 3 p. 834 - 843
