顺-2-甲基-7-十八烯合成路线 （共 56 条）
反应条件
triphenylphosphine hydroiodide; triphenylphospine diiodide in hexane; benzene 1.) 24 h, 0 deg C, 2.) 24 h, room temp.;
参考文献
Sonnet, Philip E.
Synthesis, 1980 , # 10 p. 828 - 830
反应条件
hydrogen; Pd-BaSO4 in pyridine 12 h; Yield given. Yields of byproduct given;
参考文献
Prestwich, Glenn D.; Graham, Steven McG.; Kuo, Jing-Wen; Vogt, Richard G.
Journal of the American Chemical Society, 1989 , vol. 111, # 2 p. 636 - 642
反应条件
potassium tert-butylate in tetrahydrofuran T=-10°C; 1 h;
参考文献
Ujvary, Istvan; Voigt, Erzsebet; Lesko, Katalin
Acta Chimica Hungarica, 1988 , vol. 125, # 1 p. 131 - 140
反应条件
1: 1) Li, liq.NH3, Fe(NO3)3 / 1) THF, 1 h, 2) THF, 2 h 2: 95 percent / H2 / Lindlar's catalyst / hexane 3: 90 percent / NEt3 / CH2Cl2 / 0 °C 4: 1) Mg, 2) HMPA / 1) THF, 2) THF, r.t., overnight View Scheme
参考文献
Jonas, Jaroslav; Slanina, Pavel; Humpa, Otakar; Mazal, Ctibor
Collection of Czechoslovak Chemical Communications, 1988 , vol. 53, # 4 p. 857 - 859
反应条件
1: 1.) ICl; 2.) aq. KF / 1.) CCl4, 15 min; 2.) DMSO, RT, 4 h 2: (Ph3P)4Pd / tetrahydrofuran / Ambient temperature View Scheme
参考文献
Koumaglo, K.; Chan, T. H.
Tetrahedron Letters, 1984 , vol. 25, # 7 p. 717 - 720
反应条件
hydrogen; Lindlar's catalyst in ethanol Ambient temperature; Yield given;
参考文献
Odinokov, V. N.; Balezina, G. G.; Dzhemilev, U. M.; Ishmuratov, G. Yu.; Amirkhanov, D. V.; et al.
Chemistry of Natural Compounds, 1983 , vol. 19, # 5 p. 593 - 597
Khimiya Prirodnykh Soedinenii, 1983 , # 5 p. 630 - 634
反应条件
tetrakis(triphenylphosphine) palladium(0)
参考文献
Koumaglo, K.; Chan, T. H.
Tetrahedron Letters, 1984 , vol. 25, # 7 p. 717 - 720
反应条件
1.1: 68.4 percent / MoCl5/SiO2; SnMe4 / toluene / 24 h / 20 °C / 19000 Torr 2.1: 9-BBN / tetrahydrofuran / 6 - 25 °C 2.2: 35 percent / MeONa; I2 / methanol; tetrahydrofuran / -20 °C 3.1: tetrahydrofuran / -70 - 25 °C 4.1: 9-BBN 4.2: I2; MeONa 5.1: tetrahydrofuran / -70 - 25 °C View Scheme
参考文献
Bykov, Victor I.; Butenko, Tamara A.; Petrova, Elena B.; Finkelshtein, Eugene Sh.
Tetrahedron, 1999 , vol. 55, # 27 p. 8249 - 8252
反应条件
1: KO-tBu, n-BuLi / hexane; diethyl ether / -78 deg C up to RT for 17 h 2: 1.) ICl; 2.) aq. KF / 1.) CCl4, 15 min; 2.) DMSO, RT, 4 h 3: (Ph3P)4Pd / tetrahydrofuran / Ambient temperature View Scheme
参考文献
Chan, T. H.; Koumaglo, K.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 109 - 120
反应条件
1: Na / 1) NH3(l); 2) DMF, 1 h 2: n-BuLi / 1) diglyme, 80-90 deg C, 6 h; 2) 130-140 deg C, 60 h 3: H2 / Lindlar / ethanol / Ambient temperature View Scheme
参考文献
Jonas, Jaroslav; Slanina, Pavel; Humpa, Otakar; Mazal, Ctibor
Collection of Czechoslovak Chemical Communications, 1988 , vol. 53, # 4 p. 857 - 859
