顺-2-甲基-7-十八烯合成路线 （共 56 条）
反应条件
1: tetrahydrofuran / -70 - 25 °C 2: tetrahydrofuran / -70 - 25 °C View Scheme
参考文献
Bykov; Goletiani; Butenko; Finkel'shtein
Doklady Chemistry, 2002 , vol. 384, # 4-6 p. 163 - 166
反应条件
1: 1.) KOtBu, n-BuLi / 1.) hexane, 30 min, -78 deg C, ether, warmed to room temp. 3.5 h, 2.) -78 deg C, ether, warmed to room temp. 17 h 2: 83 percent / ICl/KF 3: 90 percent / (PhP)4Pd View Scheme
参考文献
Koumaglo, K.; Chan, T. H.
Tetrahedron Letters, 1984 , vol. 25, # 7 p. 717 - 720
反应条件
1: dimethylformamide 2: (i) K, HMPT, (ii) /BRN= 1753213/ View Scheme
参考文献
Bestmann,H.J.; Vostrowsky,O.
Tetrahedron Letters, 1974 , p. 207 - 208
反应条件
sodium hydroxide; sodium tetrahydroborate; iodine; benzene-1,2-diol; magnesium 2.) benzene, reflux; 3.) THF, 25 deg C; 4.) THF, -10 deg C; Yield given. Multistep reaction;
参考文献
Periasamy, Mariappan; Bhanu Prasad; Suseela, Yantrapragada
Tetrahedron, 1995 , vol. 51, # 9 p. 2743 - 2748
反应条件
(i) HCl, (ii) NBS, (iii) NaI, DMF; Multistep reaction;
参考文献
Sonnet,P.E.; Oliver,J.E.
Journal of Organic Chemistry, 1976 , vol. 41, # 20 p. 3284 - 3286
反应条件
sodium hexamethyldisilazane 1.) THF, reflux, 2 h, 2.) THF, a) -78 deg C, 2 h, b) RT, 12 h; Yield given. Multistep reaction;
参考文献
Pikul, Stanislaw; Raczko, Jerzy; Jurczak, Janusz
Bulletin of the Polish Academy of Sciences, Chemistry, 1987 , vol. 35, # 7-8 p. 297 - 299
反应条件
N,N,N',N',N'',N''-hexamethylphosphoric triamide; magnesium 1) THF, 2) THF, r.t., overnight; Yield given. Multistep reaction;
参考文献
Vig, O. P.; Sharma, M. L.; Kumari, Sarla; Vohra, Neelam
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1985 , vol. 24, p. 860 - 861
反应条件
bis-triphenylphosphine-palladium(II) chloride; Cl2Ni(1,2-bis(diphenylphosphino)ethane) 1.) ether, room temp., 1 h, 2.) ether, room temp., 12 h.; Yield given. Multistep reaction;
参考文献
Fiandanese, Vito; Marchese, Giuseppe; Naso, Francesco; Ronzini, Ludovico
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1985 , p. 1115 - 1120
反应条件
1: (i) Mg, I2, THF, (ii) /BRN= 2234629/, LiCl, CuCl2 2: (i) Mg, I2, THF, (ii) /BRN= 2244489/, LiCl, CuCl2 View Scheme
参考文献
Tolstikov,G.A. et al.
Doklady Chemistry, 1978 , vol. 239, p. 174 - 177
Dokl. Akad. Nauk SSSR Ser. Khim., 1978 , vol. 239, p. 1377 - 1380
反应条件
1: (i) Mg, I2, THF, (ii) /BRN= 2234629/, LiCl, CuCl2 2: (i) Mg, I2, THF, (ii) /BRN= 2244489/, LiCl, CuCl2 View Scheme
参考文献
Tolstikov,G.A. et al.
Doklady Chemistry, 1978 , vol. 239, p. 174 - 177
Dokl. Akad. Nauk SSSR Ser. Khim., 1978 , vol. 239, p. 1377 - 1380
