in tetrahydrofuran byproducts: 2,4,6-tri-t-butylbenzene; -78°C; (1)H NMR data and IR investigation of the mixt. of HSiCl3 and DSiCl3 distilled off after decompn. with ethereal DCl;
参考文献
Oehme, H.; Weiss, H.
Journal of Organometallic Chemistry, 1987 , vol. 319, p. C16 - C18
hydrogenchloride in tetrahydrofuran; diethyl ether byproducts: LiCl; addn. of soln. of BrSiCl3 in THF to soln. of org.compd. in THF (-78°C), stirring (1 h, -78°C), addn. of HCl in ether; not isolated; (1)H-NMR spectrometry;
参考文献
Weiss, H.; Oehme, H.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1989 , vol. 572, p. 186 - 191
in hexane N2; reflux for 6 h; removal of the salt;; solvent removal under reduced pressure; recrystn. of the residue from pentane at -20 ° C; elem. anal.;;
hydrogenchloride in tetrahydrofuran; diethyl ether byproducts: LiCl; addn. of soln. of BrSiCl3 in THF to soln. of org.compd. in THF (-78°C), stirring (1 h, -78°C), addn. of HCl in ether; not isolated; (1)H-NMR spectrometry;
参考文献
Weiss, H.; Oehme, H.
Zeitschrift fuer Anorganische und Allgemeine Chemie, 1989 , vol. 572, p. 186 - 191
