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乙二醇
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63148-62-9
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二甲基亚砜
碳酸氢钠
471-34-1
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乙二醇
甲醛
63148-62-9
MDI
丁酮
二甲基亚砜
碳酸氢钠
471-34-1
35388-57-9
合成路线
(共 7 条)
51705-36-3
→
反应条件
35388-57-9
反应条件
potassium hydroxide in methanol Hydrolysis; 1 h; Heating;
参考文献
Toshima, Hiroaki; Saito, Masatoshi; Yoshihara, Teruhiko
Bioscience, Biotechnology and Biochemistry, 1999 , vol. 63, # 5 p. 964 - 967
156-39-8
4-羟苯基丙酮酸
→
反应条件
35388-57-9
反应条件
1: diethyl ether; tetrahydrofuran / 0.17 h / 0 °C 2: benzene / 2 h / Heating 3: 99 percent / imidazole / dimethylformamide / 5 h / 20 °C 4: K3Fe(CN)6; K2CO3; MeSO2NH2 / dihydroquinidine 1,4-anthraquinonediyl diether / 2-methyl-propan-2-ol; H2O / 24 h / 4 °C 5: 99 percent / Amberlite IR-120B (H+-form) / methanol / 38 h / Heating 6: 95 percent / KOH / methanol / 1 h / Heating View Scheme
参考文献
Toshima, Hiroaki; Saito, Masatoshi; Yoshihara, Teruhiko
Bioscience, Biotechnology and Biochemistry, 1999 , vol. 63, # 5 p. 964 - 967
154722-74-4
→
反应条件
35388-57-9
反应条件
1: benzene / 2 h / Heating 2: 99 percent / imidazole / dimethylformamide / 5 h / 20 °C 3: K3Fe(CN)6; K2CO3; MeSO2NH2 / dihydroquinidine 1,4-anthraquinonediyl diether / 2-methyl-propan-2-ol; H2O / 24 h / 4 °C 4: 99 percent / Amberlite IR-120B (H+-form) / methanol / 38 h / Heating 5: 95 percent / KOH / methanol / 1 h / Heating View Scheme
参考文献
Toshima, Hiroaki; Saito, Masatoshi; Yoshihara, Teruhiko
Bioscience, Biotechnology and Biochemistry, 1999 , vol. 63, # 5 p. 964 - 967
240405-25-8
→
反应条件
35388-57-9
反应条件
1: 99 percent / imidazole / dimethylformamide / 5 h / 20 °C 2: K3Fe(CN)6; K2CO3; MeSO2NH2 / dihydroquinidine 1,4-anthraquinonediyl diether / 2-methyl-propan-2-ol; H2O / 24 h / 4 °C 3: 99 percent / Amberlite IR-120B (H+-form) / methanol / 38 h / Heating 4: 95 percent / KOH / methanol / 1 h / Heating View Scheme
参考文献
Toshima, Hiroaki; Saito, Masatoshi; Yoshihara, Teruhiko
Bioscience, Biotechnology and Biochemistry, 1999 , vol. 63, # 5 p. 964 - 967
240405-26-9
→
反应条件
35388-57-9
反应条件
1: K3Fe(CN)6; K2CO3; MeSO2NH2 / dihydroquinidine 1,4-anthraquinonediyl diether / 2-methyl-propan-2-ol; H2O / 24 h / 4 °C 2: 99 percent / Amberlite IR-120B (H+-form) / methanol / 38 h / Heating 3: 95 percent / KOH / methanol / 1 h / Heating View Scheme
参考文献
Toshima, Hiroaki; Saito, Masatoshi; Yoshihara, Teruhiko
Bioscience, Biotechnology and Biochemistry, 1999 , vol. 63, # 5 p. 964 - 967
240405-27-0
→
反应条件
35388-57-9
反应条件
1: 99 percent / Amberlite IR-120B (H+-form) / methanol / 38 h / Heating 2: 95 percent / KOH / methanol / 1 h / Heating View Scheme
参考文献
Toshima, Hiroaki; Saito, Masatoshi; Yoshihara, Teruhiko
Bioscience, Biotechnology and Biochemistry, 1999 , vol. 63, # 5 p. 964 - 967
2746-25-0
4-甲氧基溴苄
+
79917-78-5
→
反应条件
35388-57-9
+
79917-87-6
反应条件
hydrogenchloride 2.) methanol, water; Yield given. Multistep reaction. Title compound not separated from byproducts;
参考文献
Naef, Reto; Seebach, Dieter
Angewandte Chemie, 1981 , vol. 93, # 12 p. 1113