1,1,1-三溴-2,2,2-三氟乙烷合成路线 (共 16 条)
反应条件
aluminium trichloride 22 h; Heating;
参考文献
Chambers, Richard D.; Proctor, Lee D.; Caporiccio, Gerardo
Journal of Fluorine Chemistry, 1995 , vol. 70, # 2 p. 241 - 248
反应条件
aluminium trichloride T=50 - 55°C; 22 h; Further byproducts given;
参考文献
Hemer,I.; Posta,A.
Journal of Fluorine Chemistry, 1984 , vol. 26, p. 467
参考文献
Purdue Research Found.
Patent: US2644845 , 1947 ;
反应条件
aluminium trichloride T=50 - 55°C; 22 h; Further byproducts given;
参考文献
Hemer,I.; Posta,A.
Journal of Fluorine Chemistry, 1984 , vol. 26, p. 467
参考文献
Purdue Research Found.
Patent: US2644845 , 1947 ;
参考文献
McBee et al.
Industrial and Engineering Chemistry, 1947 , vol. 39, p. 421
Journal of the American Chemical Society, 1947 , vol. 69, p. 946
反应条件
sodium hypophosphite; sodium acetate; platinum on activated charcoal in acetic acid T=40°C; 6 h;
参考文献
Hu, Chang-Ming; Tu, Ming-Hu
Journal of Fluorine Chemistry, 1991 , vol. 55, # 1 p. 101 - 104
反应条件
ammonium hydroxide; copper(l) chloride in dimethyl sulfoxide T=20°C; 24 h;
参考文献
Nenajdenko, Valentine G.; Varseev, Georgy N.; Shastin, Alexey V.; Balenkova, Elisabeth S.
Journal of Fluorine Chemistry, 2005 , vol. 126, # 6 p. 907 - 913
反应条件
ammonium hydroxide; copper(l) chloride in dimethyl sulfoxide T=20°C; 24 h; Title compound not separated from byproducts;
参考文献
Nenajdenko, Valentine G.; Varseev, Georgy N.; Shastin, Alexey V.; Balenkova, Elisabeth S.
Journal of Fluorine Chemistry, 2005 , vol. 126, # 6 p. 907 - 913
反应条件
sodium hypophosphite; sodium acetate; platinum on activated charcoal in acetic acid T=30°C; 2 h;
参考文献
Hu, Chang-Ming; Tu, Ming-Hu
Journal of Fluorine Chemistry, 1991 , vol. 55, # 1 p. 101 - 104