1,1,1,2,3,3,3-七氟代-2-三氟代甲基丙烷合成路线 （共 16 条）
反应条件
cobalt(III) fluoride T=175 - 325°C;
参考文献
Barber et al.
Journal of the American Chemical Society, 1951 , vol. 73, p. 4241
反应条件
fluorine 3 h; Irradiationaerosol; Yield given;
参考文献
Adcock, James L.; Evans, William D.; Heller-Grossman, Lilly
Journal of Organic Chemistry, 1983 , vol. 48, # 25 p. 4953 - 4957
反应条件
fluorine T=-120 - 20°C; 336 h; Yield given. Yields of byproduct given;
参考文献
Huang, Hsu-Nan; Persico, Daniel F.; Lagow, Richard J.; Clark, Leland C.
Journal of Organic Chemistry, 1988 , vol. 53, p. 78 - 85
反应条件
cobalt(III) fluoride T=360°C; 3 h; Further byproducts given;
参考文献
Burdon, James; Creasey, Jeremy C.; Proctor, Lee D.; Plevey, Raymond G.; Yeoman, J.R. Neil
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1991 , # 4 p. 445 - 447
反应条件
fluorine T=-30 - 10°C; Irradiationsteady-state flow process; the hydrocarbon vapor is condensed onto a NaF preaerosol and then subjected to attack by an excess of elemental F in He at first in the dark, then under UV irradiation; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Adcock, James L.; Evans, William D.
Journal of Organic Chemistry, 1984 , vol. 49, # 15 p. 2719 - 2723
反应条件
fluorine T=-120 - 20°C; 336 h; Yield given. Yields of byproduct given;
参考文献
Huang, Hsu-Nan; Persico, Daniel F.; Lagow, Richard J.; Clark, Leland C.
Journal of Organic Chemistry, 1988 , vol. 53, p. 78 - 85
反应条件
fluorine T=-30 - 10°C; Irradiationsteady-state flow process; the hydrocarbon vapor is condensed onto a NaF preaerosol and then subjected to attack by an excess of elemental F in He at first in the dark, then under UV irradiation; MechanismProduct distribution;
参考文献
Adcock, James L.; Evans, William D.
Journal of Organic Chemistry, 1984 , vol. 49, # 15 p. 2719 - 2723
反应条件
cobalt(III) fluoride T=140 - 230°C; Further byproducts given. Yields of byproduct given;
参考文献
Burdon, James; Ezmirly, Saleh T.; Huckerby, Thomas N.
Journal of Fluorine Chemistry, 1988 , vol. 40, p. 283 - 318
反应条件
cobalt(III) fluoride T=140 - 230°C; Yield given. Further byproducts given. Title compound not separated from byproducts;
参考文献
Burdon, James; Ezmirly, Saleh T.; Huckerby, Thomas N.
Journal of Fluorine Chemistry, 1988 , vol. 40, p. 283 - 318
反应条件
fluorine 2 h; Irradiationvar. F/hydrocarbon mole ratio, without irradiation; Product distribution;
参考文献
Adcock, James L.; Evans, William D.; Heller-Grossman, Lilly
Journal of Organic Chemistry, 1983 , vol. 48, # 25 p. 4953 - 4957
