1,8-diazabicyclo[5.4.0]undec-7-ene; bis(η3-allyl-μ-chloropalladium(II)); triethyl phosphite in tetrahydrofuran T=20°C; 20 h; Title compound not separated from byproducts.;

bis(η3-allyl-μ-chloropalladium(II)); 2,2'-bis-(diphenylphosphino)-1,1'- binaphthyl in tetrahydrofuran T=20°C;

1: 78 percent / Et3N / CH2Cl2 / 20 °C 2: [Pd(η3-C3H5)Cl]2; BINAP / tetrahydrofuran / 20 °C View Scheme

C21H38AuClNP*C24BF20(1-)*K(1+) in benzene-d6 T=90°C; Markovnikov hydroamination; 12 h; Inert atmosphere;

1: triethylamine; 4-(N,N-dimethlyamino)pyridine / dichloromethane / 20 °C / |Inert atmosphere 2: bis(η3-allyl-μ-chloropalladium(II)); triethyl phosphite; triethylamine / tetrahydrofuran / 24 h / 20 °C / |Inert atmosphere View Scheme