in further solvent(s) solid XeF2 added in small portions to a cold (-30°C) stirred soln. of trans-C4F9CF=CFBF2 in 1,1,1,3,3-perfluorobutane; soln. stirred at -30°C for 1 h and then kept for 30 min without stirring; not isolated; detected by (19)F-NMR;
参考文献
Zeitschrift fur Anorganische und Allgemeine Chemie, , vol. 629, # 14 p. 2499 - 2508
in dichloromethane solid XeF2 added in one portion to a cold (-45°C) stirred emulsion of trans-C4F9CF=CFBF2 in CH2Cl2; soln. stirred at -40°C for 3 h; soln. phase decanted from the oil phase; treatment of the oil with cold (-40°C) anhydrous HF; not isolated; detected by (19)F-NMR;
参考文献
Zeitschrift fur Anorganische und Allgemeine Chemie, , vol. 629, # 14 p. 2499 - 2508
in an ESR tube in 1,2,2-trifluoro-trichloroethane T=-30°C; 0.5 h; the reaction mixture was analyzed quantitatively by ESR, by NMR and GC; Product distribution;
参考文献
Journal of Fluorine Chemistry, , vol. 31, p. 417 - 424
