2,2,3,3,4,4,5,5-八氟-1-戊醇合成路线 （共 86 条）
反应条件
pyridine; trichlorophosphate
参考文献
Du Pont de Nemours and Co.
Patent: US2597702 , 1950 ;
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Du Pont de Nemours and Co.
Patent: US2559749 , 1950 ;
反应条件
hydroquinone; sulfonated coal; sulfuric acid in toluene T=100°C;
参考文献
Gol'din; Averbakh; Nekrasova; Lavygin; Leitan; Chalbysheva
Journal of applied chemistry of the USSR, 1985 , vol. 58, # 6 pt 2 p. 1244 - 1247
参考文献
Du Pont de Nemours and Co.
Patent: US2628958 , 1950 ;
反应条件
sulfonated coal; sulfuric acid; hydroquinone in toluene T=110°C; 6 h;
参考文献
Gol'din; Averbakh; Nekrasova; Lavygin; Leitan; Chalbysheva
Journal of applied chemistry of the USSR, 1985 , vol. 58, # 6 pt 2 p. 1244 - 1247
反应条件
1: Py 2: Cl2 / Irradiation 3: (heating) View Scheme
参考文献
Brace,N.O.; McCormack,W.B.
Journal of Organic Chemistry, 1961 , vol. 26, p. 5091 - 5099
反应条件
sodium hypochlorite; 2,2,6,6-tetramethyl-1-piperidinyloxy, free radical; potassium bromide in acetonitrile T=20°C; pH=8 - 9; 48 h; Product distribution / selectivity;
参考文献
Ignatowska, Jolanta; Shyshkov, Oleg; Zipplies, Tilman; Hintzer, Klaus; Roeschenthaler, Gerd-Volker
Journal of Fluorine Chemistry, 2012 , vol. 141, p. 35 - 40
反应条件
2: 60 percent / KOH / dimethylsulfoxide 3: 86 percent / SO2Cl2 / CH2Cl2 / 2 h / Ambient temperature View Scheme
参考文献
Portella, Charles; Shermolovich, Yuri G.; Tschenn, Olivier
Bulletin de la Societe Chimique de France, 1997 , vol. 134, # 7 p. 697 - 702
反应条件
potassium hydroxide in benzene T=80°C; 1 h;
参考文献
Shilin, S. V.; Florensova, O. N.; Chernov, N. F.; Voronkov, M. G.
J. Gen. Chem. USSR (Engl. Transl.), 1991 , vol. 61, # 8.2 p. 1838 - 1840,1697 - 1699
反应条件
1: bis(trichloromethyl) carbonate With pyridine in pentane T=-15°C; 1 h; 2: 2,2,3,3,4,4,5,5-octafluoro-1-pentanol in pentane T=-15°C; 6 h;
参考文献
Helvetica Chimica Acta, , vol. 87, # 2 p. 370 - 375
反应条件
thionyl chloride; N,N-dimethyl-formamide T=-15 - 25°C;
参考文献
Rakhimov
Russian Journal of General Chemistry, 2010 , vol. 80, # 8 p. 1626 - 1645
