6,7,8,9-四氢-5H-苯并环庚烯-5-醇合成路线 （共 17 条）
反应条件
3 A molecular sieve; oxygen; (-)-sparteine; Pd(MeCN)Cl2 in 1,2-dichloro-ethane T=70°C; 20 h; Title compound not separated from byproducts;
参考文献
Kunisu, Takashi; Oguma, Takuya; Katsuki, Tsutomu
Journal of the American Chemical Society, 2011 , vol. 133, # 33 p. 12937 - 12939
反应条件
1: With C28H36ClMnN2O2; potassium acetate in dichloromethane; water 0.0833333 h; 2: With N-bromosuccinmide in dichloromethane; water T=20°C; 2 h; Kinetics; enantioselective reaction;
参考文献
Xu, Daqian; Wang, Shoufeng; Shen, Zhiqiang; Xia, Chungu; Sun, Wei
Organic and Biomolecular Chemistry, 2012 , vol. 10, # 14 p. 2730 - 2732
反应条件
1: 90 percent / p-toluenesulfonic acid / benzene / 24 h / Heating 2: 71 percent / m-chloroperbenzoic acid / CH2Cl2 / 3 h / 0 °C 3: 89 percent / LiAlH4 / diethyl ether / 2.5 h / 0 °C 4: CrO3, H2SO4 / acetone / 2 h / Ambient temperature View Scheme
参考文献
Fujita
Yakugaku Zasshi, 1959 , vol. 79, p. 1192,1195
Chem.Abstr., 1960 , p. 3353
反应条件
1: KHSO4 / 160 - 170 °C 2: SeO2 View Scheme
参考文献
Christol et al.
Bulletin de la Societe Chimique de France, 1959 , p. 1238,1242
反应条件
toluene-4-sulfonic acid in benzene
1 h; Heating;
参考文献
Prasad, Mohan; Rastogi, Shri Niwas
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1984 , vol. 23, # 8 p. 753 - 757
反应条件
tetrachlorosilane in chloroform
T=20°C; 4.5 h;
参考文献
Firouzabadi, Habib; Iranpoor, Naser; Karimi, Babak; Hazarkhani, Hassan
Synthetic Communications, 2003 , vol. 33, # 21 p. 3671 - 3677
反应条件
1: 16.79 g / p-TsOH*H2O / benzene / 4 h / Heating
2: 68 percent / NBS; benzoyl peroxide / CCl4 / 2 h / Irradiation; heating
3: 12 percent / SeO2; KH2PO4 / dioxane; H2O / 16 h / Heating
View Scheme
参考文献
Bonvallet, Paul A.; Todd, Eric M.; Kim, Yong Seol; McMahon, Robert J.
Journal of Organic Chemistry, 2002 , vol. 67, # 25 p. 9031 - 9042
