Pd[P(o-tol)3]2; CyPF-t-Bu; ammonia; sodium t-butanolate in 1,4-dioxane T=50°C; 24 h; Inert atmosphere;

in pyridine T=45°C; 15 h;

1.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 12 h / 23 °C / |Inert atmosphere 2.1: toluene-4-sulfonic acid / dichloromethane / 0.08 h / 23 °C / |Inert atmosphere 2.2: 0.5 h / 20 °C / |Inert atmosphere 3.1: acetonitrile / 23 °C / |Electrochemical reaction View Scheme

1.1: 3-chloro-benzenecarboperoxoic acid / dichloromethane / 12 h / 23 °C / |Inert atmosphere 2.1: toluene-4-sulfonic acid / dichloromethane / 0.08 h / 23 °C / |Inert atmosphere 2.2: 0.5 h / 20 °C / |Inert atmosphere 3.1: acetonitrile / 23 °C / |Electrochemical reaction View Scheme

View Scheme

暂无反应条件数据

potassium phosphate; Ni(PCy3)2Cl2; tri-cyclo-hexyl-phosphine in 1,4-dioxane T=130°C; Suzuki cross-coupling;

(R)-(S)-PPF-PtBu2; Pd(P(o-Tol)3)2 in diethyl ether; toluene T=80°C; Kumada coupling;