(1R,2R,4S)-rel-双环[2.2.1]庚烷-2-甲醛合成路线 （共 14 条）
反应条件
methanesulfonic acid; Pt(C2H4)(1,3-bis(diphenylphosphino)butane); hydrogen in toluene T=100°C; P=76000 Torr; 5 h; also 2,5-norbornadiene; other catalysts, var. temp. and reaction time; also reaction with D2; Product distribution;
参考文献
Botteghi, C.; Paganelli, S.; Perosa, A.; Lazzaroni, R.; Uccello-Barretta, G.
Journal of Organometallic Chemistry, 1993 , vol. 447, # 1 p. 153 - 157
反应条件
boron trifluoride diethyl etherate; water; mercury(II) oxide in tetrahydrofuran 0.25 h; Ambient temperature;
参考文献
Brown, Herbert C.; Imai, Toshiro
Journal of Organic Chemistry, 1984 , vol. 49, # 5 p. 892 - 898
反应条件
hydrogen; palladium on activated charcoal in methanol
参考文献
Freeman,P.K.; Desai,K.B.
Journal of Organic Chemistry, 1971 , vol. 36, p. 1554 - 1558
反应条件
[(dppf)Pt(H2O)2](OTf)2; hydrogen; sodium lauryl sulfate in water T=70°C; P=60006 Torr; 22 h; Autoclave; optical yield given as percent de;
参考文献
Gottardo, Marina; Scarso, Alessandro; Paganelli, Stefano; Strukul, Giorgio
Advanced Synthesis and Catalysis, 2010 , vol. 352, # 13 p. 2251 - 2262
反应条件
oxalyl dichloride; dimethyl sulfoxide; triethylamine in dichloromethane 1.) -78 deg C, 20 min; Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Teager, David S.; Ward, Harry D.; Murray, Roger K.
Journal of Organic Chemistry, 1993 , vol. 58, # 20 p. 5493 - 5499
反应条件
tetrafluoroboric acid; mercury(II) oxide in tetrahydrofuran 0.25 h; Heating; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Ceruti, Maurizio; Degani, Iacopo; Fochi, Rita
Synthesis, 1987 , # 1 p. 79 - 82
反应条件
1: Et3Al, Co(acac)3 / benzene / 4 h / 40 °C 2: O3, PPh3 / methanol; diethyl ether View Scheme
参考文献
Sato,H.; Inukai,T.
Bulletin of the Chemical Society of Japan, 1972 , vol. 45, p. 944 - 945
反应条件
Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Brown; Imai
Journal of the American Chemical Society, 1983 , vol. 105, # 20 p. 6285 - 6289
反应条件
in diethyl ether 0.5 h; Ambient temperature; Yield given. Title compound not separated from byproducts;
参考文献
Olah, George A.; Ohannesian, Lena; Arvanaghi, Massoud
Journal of Organic Chemistry, 1984 , vol. 49, # 20 p. 3856 - 3857
反应条件
nitrogen; sodium carbonate
参考文献
Alder; Stein
Justus Liebigs Annalen der Chemie, 1936 , vol. 525, p. 247,252, 258
