2,3,4,5,6,7,8,8a-八氢-1H-萘-4a-醇合成路线 （共 47 条）
反应条件
diazofluorene-O2 in dichloromethane Irradiation;
参考文献
Smith, John R. Lindsay; Sleath, Paul R.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , p. 1165 - 1170
反应条件
1: 85 percent / trifluoroacetic acid; CH2Cl2 / 0.17 h / 0 °C 2: 74 percent / H2 / Pd/C / methanol / 1.2 h / 760 Torr View Scheme
参考文献
Chu, Yongliang; Colclough, David; Hotchkin, David; Tuazon, Myla; White, James B.
Tetrahedron, 1997 , vol. 53, # 42 p. 14235 - 14246
反应条件
1: 74 percent / SnCl4 / CH2Cl2 / 0.33 h / -78 °C / other reagent 2: 74 percent / H2 / Pd/C / methanol / 1.2 h / 760 Torr View Scheme
参考文献
Chu, Yongliang; Colclough, David; Hotchkin, David; Tuazon, Myla; White, James B.
Tetrahedron, 1997 , vol. 53, # 42 p. 14235 - 14246
反应条件
Δ-[Fe(CF3SO3)2((R,R,R)-MCPP)]; dihydrogen peroxide; acetic acid in acetonitrile Reagent/catalyst; Overall yield = 51 percentChromat.; regioselective reaction;
参考文献
Canta, Merce; Font, David; Gomez, Laura; Ribas, Xavi; Costas, Miquel
Advanced Synthesis and Catalysis, 2014 , vol. 356, # 4 p. 818 - 830
反应条件
zinc; (Fe3O(OAc)6)(C5H5N)3.5 in pyridine; water; acetic acid 20 h; Ambient temperature; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Belavoine, Gilbert; Barton, Derek H. R.; Boivin, Jean; Gref, Aurore; Coupanec, Pascale Le; et al.
Tetrahedron, 1988 , vol. 44, # 4 p. 1091 - 1106
反应条件
(Fe3O(OAc)6)(C6H5N)3.5 in pyridine; water; trifluoroacetic acid T=25 - 30°C; 15-20 mA/cm2; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Belavoine, Gilbert; Barton, Derek H. R.; Boivin, Jean; Gref, Aurore; Coupanec, Pascale Le; et al.
Tetrahedron, 1988 , vol. 44, # 4 p. 1091 - 1106
反应条件
5,10,15,20-tetra(o-tolyl)porphyrin iron(III) chloride; iodosylbenzene in dichloromethane influence of the amount and nature of catalyst; Product distribution;
参考文献
Mimoun; Saussine; Daire; Postel; Fischer; Weiss
Journal of the American Chemical Society, 1983 , vol. 105, # 10 p. 3101 - 3110
反应条件
meta-chloroperoxybenzoic acid in benzene T=100°C; 3 h; stereoselectivity of hydroxylation; Rate constantProduct distribution;
参考文献
Smith, John R. Lindsay; Sleath, Paul R.
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1983 , p. 1165 - 1170
反应条件
1: 91 percent / PCC, NaOAc, molecular sieves / CH2Cl2 / 0.25 h / 0 °C 2: 85 percent / conc. aq. HCl / CH2Cl2 / Ambient temperature 3: 73 percent / (n-Bu)3SnH, AIBN / benzene / 16 h / Heating View Scheme
参考文献
Colclough, David; White, James B.; Smith, William B.; Chu, Yongliang
Journal of Organic Chemistry, 1993 , vol. 58, # 23 p. 6303 - 6313
反应条件
1: 85 percent / conc. aq. HCl / CH2Cl2 / Ambient temperature 2: 73 percent / (n-Bu)3SnH, AIBN / benzene / 16 h / Heating View Scheme
参考文献
Colclough, David; White, James B.; Smith, William B.; Chu, Yongliang
Journal of Organic Chemistry, 1993 , vol. 58, # 23 p. 6303 - 6313
