2,3,4,5,6,7,8,8a-八氢-1H-萘-4a-醇合成路线 （共 47 条）
反应条件
1: 62 percent / imidazole / dimethylformamide / 2 h / Ambient temperature 2: 60 percent / ethanol / 3 h / Heating 3: 68 percent / n-BuLi, TMEDA / hexane / 1 h / 0 °C 4: 88 percent / (n-Bu)4NF / tetrahydrofuran / 48 h / Ambient temperature 5: 91 percent / PCC, NaOAc, molecular sieves / CH2Cl2 / 0.25 h / 0 °C 6: 85 percent / conc. aq. HCl / CH2Cl2 / Ambient temperature 7: 73 percent / (n-Bu)3SnH, AIBN / benzene / 16 h / Heating View Scheme
参考文献
Colclough, David; White, James B.; Smith, William B.; Chu, Yongliang
Journal of Organic Chemistry, 1993 , vol. 58, # 23 p. 6303 - 6313
反应条件
1: 60 percent / ethanol / 3 h / Heating 2: 68 percent / n-BuLi, TMEDA / hexane / 1 h / 0 °C 3: 88 percent / (n-Bu)4NF / tetrahydrofuran / 48 h / Ambient temperature 4: 91 percent / PCC, NaOAc, molecular sieves / CH2Cl2 / 0.25 h / 0 °C 5: 85 percent / conc. aq. HCl / CH2Cl2 / Ambient temperature 6: 73 percent / (n-Bu)3SnH, AIBN / benzene / 16 h / Heating View Scheme
参考文献
Colclough, David; White, James B.; Smith, William B.; Chu, Yongliang
Journal of Organic Chemistry, 1993 , vol. 58, # 23 p. 6303 - 6313
反应条件
1: 88 percent / (n-Bu)4NF / tetrahydrofuran / 48 h / Ambient temperature 2: 91 percent / PCC, NaOAc, molecular sieves / CH2Cl2 / 0.25 h / 0 °C 3: 85 percent / conc. aq. HCl / CH2Cl2 / Ambient temperature 4: 73 percent / (n-Bu)3SnH, AIBN / benzene / 16 h / Heating View Scheme
参考文献
Colclough, David; White, James B.; Smith, William B.; Chu, Yongliang
Journal of Organic Chemistry, 1993 , vol. 58, # 23 p. 6303 - 6313
反应条件
1: 68 percent / n-BuLi, TMEDA / hexane / 1 h / 0 °C 2: 88 percent / (n-Bu)4NF / tetrahydrofuran / 48 h / Ambient temperature 3: 91 percent / PCC, NaOAc, molecular sieves / CH2Cl2 / 0.25 h / 0 °C 4: 85 percent / conc. aq. HCl / CH2Cl2 / Ambient temperature 5: 73 percent / (n-Bu)3SnH, AIBN / benzene / 16 h / Heating View Scheme
参考文献
Colclough, David; White, James B.; Smith, William B.; Chu, Yongliang
Journal of Organic Chemistry, 1993 , vol. 58, # 23 p. 6303 - 6313
反应条件
1: bromine / 1.) benzene, 0 deg C, 1 h, dark, 2.) sunlight, 15 min 2: 75 percent / tributylstannane, azodiisobutyronitrile / benzene / 15 h / 60 °C View Scheme
参考文献
Beckwith, Athelstan L.J.; Kazlauskas, Rymantas; Syner-Lyons, Mark R.
Journal of Organic Chemistry, 1983 , vol. 48, # 24 p. 4718 - 4722
反应条件
C36H26FeN6O14; dihydrogen peroxide in water; acetonitrile T=20°C; 20 h; Irradiation;
参考文献
Cheng, Shi; Li, Jing; Yu, Xiaoxiao; Chen, Chuncheng; Ji, Hongwei; Ma, Wanhong; Zhao, Jincai
New Journal of Chemistry, 2013 , vol. 37, # 10 p. 3267 - 3273
反应条件
samarium; iron(III) tris(dibenzoylmethane); 1,2-di-iodoethane in tetrahydrofuran 12 h; Ambient temperature; Yield given. Yields of byproduct given;
参考文献
Molander, Gary A.; Etter, Jeffrey B.
Journal of Organic Chemistry, 1986 , vol. 51, # 10 p. 1778 - 1786
反应条件
perchloric acid; dihydrogen peroxide in water; acetonitrile; tert-butyl alcohol T=59.84°C; 1 h; regioselective reaction;
参考文献
Kamata, Keigo; Yonehara, Kazuhiro; Nakagawa, Yoshinao; Uehara, Kazuhiro; Mizuno, Noritaka
Nature Chemistry, 2010 , vol. 2, # 6 p. 478 - 483
反应条件
Fe(triflate)2(1-(6-methyl-2-pyridylmethyl)-4,7-dimethyl-1,4,7-triazacyclononane); dihydrogen peroxide; acetic acid in water; acetonitrile T=0°C; 0.666667 h; Reagent/catalyst;
参考文献
Prat, Irene; Gomez, Laura; Canta, Merce; Ribas, Xavi; Costas, Miquel
Chemistry - A European Journal, 2013 , vol. 19, # 6 p. 1908 - 1913
反应条件
pyridine-2-carboxylic acid; water; Fe3O(OAc)6Pyr3.5 in pyridine; methanol T=25 - 30°C; 15-20 mA/cm2; in futher solvents; Product distribution;
参考文献
Belavoine, Gilbert; Barton, Derek H. R.; Boivin, Jean; Gref, Aurore; Coupanec, Pascale Le; et al.
Tetrahedron, 1988 , vol. 44, # 4 p. 1091 - 1106
