in tetrahydrofuran byproducts: CH3CN; addn. of 5 mL of 1E-2 M Mn(CO)5(1-) in THF to 5 mL of 1E-2 M Mn(CO)5(MeCN)(1+) in THF under Ar at 22°C, react. time <5 min; not isolated; monitored by IR;
参考文献
Lee, K. Y.; Kuchynka, D. J.; Kochi, J. K.
Organometallics, 1987 , vol. 6, p. 1886 - 1897
tetrahydrofuran; triphenylphosphine in tetrahydrofuran in 10 mL of THF with 5E-3 M Mn(CO)5(1-) and 5E-3 M Mn(CO)5(NCMe)(1+) at 22°C under Ar, 0.1 mmol PPh3 added, react. complete within 5 min;
in tetrahydrofuran byproducts: CO; addn. of 5 mL of 1E-2 M Mn(CO)5(1-) in THF to 5 mL of 1E-2 M Mn(CO)6(1+) in THF under Ar at 22°C, react. time <5 min; not isolated; monitored by IR;
参考文献
Lee, K. Y.; Kuchynka, D. J.; Kochi, J. K.
Organometallics, 1987 , vol. 6, p. 1886 - 1897
tetrahydrofuran in tetrahydrofuran addn. of 5 mL of 1E-2 M Mn(CO)5(1-) in THF to 5 mL of 1E-2 M Mn(CO)5PPh3(1+) in THF under Ar at 22°C, react. time <5 min; not isolated; monitored by IR;
tetrahydrofuran in tetrahydrofuran addn. of 5 mL of 1E-2 M Mn(CO)5(1-) in THF to 5 mL of 1E-2 M Mn(CO)5P(p-tol)3(1+) in THF under Ar at 22°C, react. time <5 min; not isolated; monitored by IR;
tetrahydrofuran in tetrahydrofuran addn. of 5 mL of 1E-2 M Mn(CO)5(1-) in THF to 5 mL of 1E-2 M Mn(CO)5PPh2Et(1+) in THF under Ar at 22°C, react. time 30 min; not isolated; detected by IR and TLC;
tetrahydrofuran; triphenylphosphine in tetrahydrofuran in 10 mL of THF with 5E-3 M Mn(CO)5(1-) and 5E-3 M Mn(CO)5(NCMe)(1+) at 22°C under Ar, 0.5 mmol PPh3 added, react. complete within 5 min;
tetrahydrofuran in tetrahydrofuran addn. of 5 mL of 1E-2 M Mn(CO)5(1-) in THF to 5 mL of 1E-2 M Mn(CO)5PPh2Me(1+) in THF under Ar at 22°C, react. time 5 min; not isolated; detected by IR and TLC;
tetrahydrofuran in tetrahydrofuran addn. of 5 mL of 1E-2 M Mn(CO)5(1-) in THF to 5 mL of 1E-2 M Mn(CO)5PPhMe2(1+) in THF under Ar at 22°C, react. time 200 min; not isolated; detected by IR and TLC;
