3-[(3E,7E,11E)-4,8,12,16-四甲基-3,7,11,15-十七四烯-1-基]呋喃合成路线 （共 6 条）
反应条件
Pd(1,3-bis(diphenylphosphino)-propane)Cl2; lithium triethylborohydride in tetrahydrofuran T=0°C; 0.5 h; Inert atmosphere;
参考文献
Kotoku, Naoyuki; Fujioka, Shinichi; Nakata, Chiaki; Yamada, Masaki; Sumii, Yuji; Kawachi, Takashi; Arai, Masayoshi; Kobayashi, Motomasa
Tetrahedron, 2011 , vol. 67, # 35 p. 6673 - 6678
反应条件
1.1: carbon tetrabromide; triphenylphosphine / dichloromethane / 0.5 h / 0 °C / Inert atmosphere 2.1: potassium tert-butylate / tetrahydrofuran / 1 h / -30 °C / Inert atmosphere 2.2: Inert atmosphere 3.1: Pd(1,3-bis(diphenylphosphino)-propane)Cl2; lithium triethylborohydride / tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere View Scheme
参考文献
Kotoku, Naoyuki; Fujioka, Shinichi; Nakata, Chiaki; Yamada, Masaki; Sumii, Yuji; Kawachi, Takashi; Arai, Masayoshi; Kobayashi, Motomasa
Tetrahedron, 2011 , vol. 67, # 35 p. 6673 - 6678
反应条件
1.1: N,N-dimethyl-formamide / 1 h / 0 °C / Inert atmosphere 2.1: potassium tert-butylate / tetrahydrofuran / 1 h / -30 °C / Inert atmosphere 2.2: Inert atmosphere 3.1: Pd(1,3-bis(diphenylphosphino)-propane)Cl2; lithium triethylborohydride / tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere View Scheme
参考文献
Kotoku, Naoyuki; Fujioka, Shinichi; Nakata, Chiaki; Yamada, Masaki; Sumii, Yuji; Kawachi, Takashi; Arai, Masayoshi; Kobayashi, Motomasa
Tetrahedron, 2011 , vol. 67, # 35 p. 6673 - 6678
反应条件
1.1: toluene / 8 h / 60 °C / Inert atmosphere 2.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.33 h / 0 °C / Inert atmosphere 2.2: Inert atmosphere 3.1: carbon tetrabromide; triphenylphosphine / dichloromethane / 0.5 h / 0 °C / Inert atmosphere 4.1: potassium tert-butylate / tetrahydrofuran / 1 h / -30 °C / Inert atmosphere 4.2: Inert atmosphere 5.1: Pd(1,3-bis(diphenylphosphino)-propane)Cl2; lithium triethylborohydride / tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere View Scheme
参考文献
Kotoku, Naoyuki; Fujioka, Shinichi; Nakata, Chiaki; Yamada, Masaki; Sumii, Yuji; Kawachi, Takashi; Arai, Masayoshi; Kobayashi, Motomasa
Tetrahedron, 2011 , vol. 67, # 35 p. 6673 - 6678
反应条件
1.1: diisobutylaluminium hydride / hexane; dichloromethane / 0.33 h / 0 °C / Inert atmosphere 1.2: Inert atmosphere 2.1: carbon tetrabromide; triphenylphosphine / dichloromethane / 0.5 h / 0 °C / Inert atmosphere 3.1: potassium tert-butylate / tetrahydrofuran / 1 h / -30 °C / Inert atmosphere 3.2: Inert atmosphere 4.1: Pd(1,3-bis(diphenylphosphino)-propane)Cl2; lithium triethylborohydride / tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere View Scheme
参考文献
Kotoku, Naoyuki; Fujioka, Shinichi; Nakata, Chiaki; Yamada, Masaki; Sumii, Yuji; Kawachi, Takashi; Arai, Masayoshi; Kobayashi, Motomasa
Tetrahedron, 2011 , vol. 67, # 35 p. 6673 - 6678
反应条件
1.1: potassium tert-butylate / tetrahydrofuran / 1 h / -30 °C / Inert atmosphere 1.2: Inert atmosphere 2.1: Pd(1,3-bis(diphenylphosphino)-propane)Cl2; lithium triethylborohydride / tetrahydrofuran / 0.5 h / 0 °C / Inert atmosphere View Scheme
参考文献
Kotoku, Naoyuki; Fujioka, Shinichi; Nakata, Chiaki; Yamada, Masaki; Sumii, Yuji; Kawachi, Takashi; Arai, Masayoshi; Kobayashi, Motomasa
Tetrahedron, 2011 , vol. 67, # 35 p. 6673 - 6678
