2-溴-1,1-二氟乙烯合成路线 （共 16 条）
参考文献
Capriel,P.; Binsch,G.
Tetrahedron, 1979 , vol. 35, p. 2661 - 2668
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Demiel,A.
Journal of Organic Chemistry, 1960 , vol. 25, p. 993 - 996
反应条件
n-butyllithium; trimethylstannyl chloride 1) -95 deg C, 2) flash vacuum pyrolysis, 800 deg C; or with alkali metals, gas phase, 300 - 550 deg C; Multistep reaction;
参考文献
Runge, Andreas; Sander, Wolfram W.
Tetrahedron Letters, 1990 , vol. 31, # 38 p. 5453 - 5456
反应条件
(i) Br2, (UV-irradiation), (ii) KOH; Multistep reaction;
参考文献
Sullivan,R. et al.
Journal of Organic Chemistry, 1964 , vol. 29, p. 3664 - 3668
参考文献
Johari,D.P. et al.
Journal of the Chemical Society [Section] B: Physical Organic, 1971 , p. 95 - 99
反应条件
hydrogen fluoride T=-10 - 60°C;
参考文献
Dickey et al.
Industrial and Engineering Chemistry, 1954 , vol. 46, p. 2213,2217
反应条件
cobalt(III) fluoride T=35°C;
参考文献
Rausch,D.A. et al.
Journal of Organic Chemistry, 1963 , vol. 28, p. 494 - 497
反应条件
tetrakis(triphenylphosphine) palladium(0); chloro-trimethyl-silane; diiodomethane; zinc 1.) THF, 60-90 deg C, 30 min, 2.) THF, 60 deg C, 4 h; Yield given. Multistep reaction. Further byproducts given;
参考文献
Nguyen, Ba V.; Burton, Donald J.
Journal of Organic Chemistry, 1997 , vol. 62, # 22 p. 7758 - 7764
反应条件
T=20°C; 240 h; γ-ray irradiation;
参考文献
Cooper, Julian A.; Copin, Elodie; Sandford, Graham
Journal of Fluorine Chemistry, 2002 , vol. 115, # 1 p. 83 - 90
反应条件
trifluoromethyl hypochlorite T=-140 - 22°C; 20 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Johri, Kamalesh K.; DesMarteau, Darryl D.
Journal of Organic Chemistry, 1983 , vol. 48, # 2 p. 242 - 250
反应条件
T=-140 - 22°C; 20 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Johri, Kamalesh K.; DesMarteau, Darryl D.
Journal of Organic Chemistry, 1983 , vol. 48, # 2 p. 242 - 250
