in pentane under N2, stirring at room temp, the react. was complete within 20-30 min; evapn. (vac.), chromy. on alumina (eluent pentane for the hydrometalated products, and more polar solvents for the dimer), the org. products identiefied by GC and NMR;
in benzene-d6 under N2 for 7-10 min (molar ratio metal hydride:diene = ca. 2:1);; detected by CIDNP studies;;
参考文献
Thomas, Marian J.; Shackleton, Thomas A.; Wright, Steven C.; Gillis, Daniel J.; Colpa, Johannes P.; Baird, Michael C.
Journal of the Chemical Society, Chemical Communications, 1986 , # 4 p. 312 - 314
in pentane under N2, stirring at room temp, the react. was complete within 20-30 min; evapn. (vac.), chromy. on alumina (eluent pentane for the hydrometalated products, and more polar solvents for the dimer), the org. products identiefied by GC and NMR;
参考文献
Shackleton, Thomas A.; Baird, Michael C.
Organometallics, 1989 , vol. 8, p. 2225 - 2232
in benzene-d6 under N2 for 7-10 min (molar ratio metal hydride:diene = ca. 2:1);; detected by CIDNP studies;;
参考文献
Thomas, Marian J.; Shackleton, Thomas A.; Wright, Steven C.; Gillis, Daniel J.; Colpa, Johannes P.; Baird, Michael C.
Journal of the Chemical Society, Chemical Communications, 1986 , # 4 p. 312 - 314
in pentane under N2, stirring at room temp, the react. was complete within 20-30 min; evapn. (vac.), chromy. on alumina (eluent pentane for the hydrometalated products, and more polar solvents for the dimer), the org. products identiefied by GC and NMR;
in pentane under N2, stirring at room temp, the react. was complete within about 1 h; evapn. (vac.), chromy. on alumina (eluent pentane for the hydrometalated products, and more polar solvents for the dimer), elem. anal., (the org. products identified by GC and NMR);
in benzene-d6 under N2 for 7-10 min (molar ratio metal hydride:diene = ca. 2:1);; detected by CIDNP studies;;
参考文献
Thomas, Marian J.; Shackleton, Thomas A.; Wright, Steven C.; Gillis, Daniel J.; Colpa, Johannes P.; Baird, Michael C.
Journal of the Chemical Society, Chemical Communications, 1986 , # 4 p. 312 - 314
in pentane under N2, stirring at room temp., about 30 min; evapn. (vac.), chromy. on alumina (eluent pentane fot the hydrometalated product, more polar solvents for the dimer), the org. product not isolated, identified by NMR;
in pentane under N2, stirring at room temp, the react. was complete within about 1 h; evapn. (vac.), chromy. on alumina (eluent pentane for the hydrometalated products, and more polar solvents for the dimer), elem. anal., (the org. products identified by GC and NMR);
in benzene-d6 under N2 for 7-10 min (molar ratio metal hydride:diene = ca. 2:1);; detected by CIDNP studies;;
参考文献
Thomas, Marian J.; Shackleton, Thomas A.; Wright, Steven C.; Gillis, Daniel J.; Colpa, Johannes P.; Baird, Michael C.
Journal of the Chemical Society, Chemical Communications, 1986 , # 4 p. 312 - 314
