3,6-二甲基-1,2-苯二胺合成路线 （共 10 条）
反应条件
hydrogenchloride; tin
参考文献
Justus Liebigs Annalen der Chemie, , vol. 228, p. 243
反应条件
ammonia in 1,3,5-trimethyl-benzene
反应条件
hydrogen; palladium on activated charcoal in ethanol; toluene
参考文献
Thulin, Bengt; Wennerstroem, Olof
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1983 , vol. 37, # 7 p. 589 - 596
参考文献
Showa Denko K.K.
Patent: US6114277 A1, 2000 ;
反应条件
1: 2.) Pd/C / 1.) nitration, 2.) toluene-EtOH 2: 51 percent / H2 / Pd/C / ethanol; toluene View Scheme
参考文献
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, , vol. 37, # 7 p. 589 - 596
反应条件
1: nitric acid / sulfuric acid / 2 h / 0 °C 2: hydrogen / 15 Pd/C / methanol / 40 °C / Inert atmosphere View Scheme
反应条件
triethylamine in tetrahydrofuran; dichloromethane; water
参考文献
Glaxo Wellcome Inc.
Patent: US6090846 A1, 2000 ;
反应条件
hydrogenchloride; sodium hydroxide in methanol; chloroform; water; acetone
参考文献
Imperial Chemical Industries Limited
Patent: US4167569 A1, 1979 ;
反应条件
1: 40 percent / NaNO2, conc. H2SO4, phosphoric acid, KI / 0 °C
2: 1.3 g / NBS, dibenzoyl peroxide / CCl4 / 24 h / Heating
View Scheme
参考文献
Thulin, Bengt; Wennerstroem, Olof
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1983 , vol. 37, # 7 p. 589 - 596
反应条件
phosphoric acid; sulfuric acid; potassium iodide; sodium nitrite
T=0°C;
参考文献
Thulin, Bengt; Wennerstroem, Olof
Acta Chemica Scandinavica, Series B: Organic Chemistry and Biochemistry, 1983 , vol. 37, # 7 p. 589 - 596
