N,N-二乙基-2,2,2-三氟乙酰胺合成路线 （共 28 条）
反应条件
n-butyllithium in tetrahydrofuran; cyclohexane T=-78°C; 1 h;
参考文献
Findlay; Fishwick; Kersey; Ward
Synthesis, 1995 , # 5 p. 553 - 556
反应条件
water in hexane
in sealed evacuated ampule; to a soln. of Et3GeLi at -78°C CF3CONEt2 added; stirred at - 78°C for 3; hydrolized; dried; CF3COGeEt3 isolated by fractionation; PMR; GLC; mass-spectrometry; elem. anal.;
参考文献
Bravo-Zhivotovskii, D. A.; Pigarev, S. D.; Kalikhman, I. D.; Vyazankina, O. A.; Vyazankin, N. S.
Journal of General Chemistry USSR (English Translation), 1983 , vol. 53, p. 1654 - 1658
Zhurnal Obshchei Khimii, 1983 , vol. 53, p. 1838 - 1843
反应条件
water in hexane
stirring (20°C, 4 h), hydrolysis; drying of org. layer (over MgSO4); elem. anal.;
参考文献
Bravo-Zhivotovskii, D. A.; Pigarev, S. D.; Vyazankina, O. A.; Kalikhman, I. D.; Vyazankin, N. S.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1982 , vol. 31, # 4 p. 841 - 843
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1982 , # 4 p. 949 - 951
反应条件
water in hexane
in sealed evacuated ampule; to a soln. of Et3GeLi at -78°C CF3CONEt2 added; stirred at - 78°C for 3; hydrolized; dried; CF3COGeEt3 isolated by fractionation; PMR; GLC; mass-spectrometry; elem. anal.;
参考文献
Bravo-Zhivotovskii, D. A.; Pigarev, S. D.; Kalikhman, I. D.; Vyazankina, O. A.; Vyazankin, N. S.
Journal of General Chemistry USSR (English Translation), 1983 , vol. 53, p. 1654 - 1658
Zhurnal Obshchei Khimii, 1983 , vol. 53, p. 1838 - 1843
反应条件
n-butyllithium in tetrahydrofuran; hexane
T=-74°C; 1.25 h;
参考文献
Fishwick, Colin W. G.; Sanderson, John M.; Findlay, John B. C.
Tetrahedron Letters, 1994 , vol. 35, # 26 p. 4611 - 4614
参考文献
Yagupol'skii,Yu.L. et al.
Journal of Organic Chemistry USSR (English Translation), 1976 , vol. 12, p. 2148 - 2151
Zhurnal Organicheskoi Khimii, 1976 , vol. 12, p. 2213 - 2217
反应条件
1: P2S5 / dioxane / Heating
2: Cl2 / CCl4
View Scheme
参考文献
Yagupol'skii,Yu.L. et al.
Journal of Organic Chemistry USSR (English Translation), 1976 , vol. 12, p. 2148 - 2151
Zhurnal Organicheskoi Khimii, 1976 , vol. 12, p. 2213 - 2217
反应条件
1: P2S5 / dioxane / Heating
2: SF4, KF
View Scheme
参考文献
Yagupol'skii,Yu.L. et al.
Journal of Organic Chemistry USSR (English Translation), 1976 , vol. 12, p. 2148 - 2151
Zhurnal Organicheskoi Khimii, 1976 , vol. 12, p. 2213 - 2217
