(3-溴丙基)三苯基溴化磷合成路线 （共 51 条）
反应条件
1: (3-bromopropyl)triphenylphosphinium bromide With ethanol; sodium hydride in ethylene glycol dimethyl ether
T=60°C; 6 h;
2: para-methylacetophenone in ethylene glycol dimethyl ether
T=70°C; Wittig olefination reaction; 20 h; Further stages.;
参考文献
Matsuda, Takanori; Tsuboi, Tomoya; Murakami, Masahiro
Journal of the American Chemical Society, 2007 , vol. 129, # 42 p. 12596 - 12597
反应条件
potassium tert-butylate in tetrahydrofuran
参考文献
Wang, Bin; Shen, Yu-Mei; Shi, Yian
Journal of Organic Chemistry, 2006 , vol. 71, # 25 p. 9519 - 9521
反应条件
potassium tert-butylate in tetrahydrofuran
参考文献
Wang, Bin; Shen, Yu-Mei; Shi, Yian
Journal of Organic Chemistry, 2006 , vol. 71, # 25 p. 9519 - 9521
反应条件
1: 76 percent / acetone; H2O / 15 h / Heating
2: 15 percent / t-BuOK / 2-methyl-propan-2-ol / 0.25 h / Ambient temperature
View Scheme
参考文献
Hercouet, A.; Corre, M. Le
Tetrahedron, 1981 , vol. 37, # 16 p. 2855 - 2860
反应条件
1: 100 percent / dimethylformamide / 4 h / Heating
2: 99 percent / 20percent aqueous sodium hydroxide / 1 h / Heating
3: 1.) trichlorosilane, triethylamine 2.) 50percent aqueous sodium hydroxide / 1.) toluene, 5 min then reflux, 2 h 2.) toluene, ice cooling, 1 h
View Scheme
参考文献
Benn, Roger F.; Briggs, Josie C.; McAuliffe, Charles A.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1984 , p. 293 - 296
反应条件
potassium tert-butylate in tetrahydrofuran
参考文献
Wang, Bin; Shen, Yu-Mei; Shi, Yian
Journal of Organic Chemistry, 2006 , vol. 71, # 25 p. 9519 - 9521
反应条件
potassium tert-butylate in tetrahydrofuran
参考文献
Wang, Bin; Shen, Yu-Mei; Shi, Yian
Journal of Organic Chemistry, 2006 , vol. 71, # 25 p. 9519 - 9521
反应条件
1: 76 percent / acetone; H2O / 15 h / Heating
2: 45 percent / t-BuOK / 2-methyl-propan-2-ol / 0.25 h / Ambient temperature
View Scheme
参考文献
Hercouet, A.; Corre, M. Le
Tetrahedron, 1981 , vol. 37, # 16 p. 2855 - 2860
反应条件
sodium hydride
1) DME, r.t. 2) DME, 70 deg C, 17 h; Yield given. Multistep reaction;
参考文献
Lechevallier, A.; Huet, F.; Conia, J. M.
Tetrahedron, 1983 , vol. 39, # 20 p. 3307 - 3316
反应条件
sodium hydride
1) THF, r.t. 2) THF, 60 deg C, 20 h; Yield given. Multistep reaction;
参考文献
Lechevallier, A.; Huet, F.; Conia, J. M.
Tetrahedron, 1983 , vol. 39, # 20 p. 3307 - 3316
